Pseudohexagonal NbO microcolumns spanning a size range of 50 to 610 nm were synthesized utilizing a cost-effective hydrothermal process (maintained at 180 °C for 30 min), followed by a subsequent calcination step at 500 °C for 3 h. Raman spectroscopy analysis unveiled three distinct reflection peaks at 220.04 cm, 602.
View Article and Find Full Text PDFTitanium dioxide nanobelts were prepared via the alkali-hydrothermal method for application in chemical gas sensing. The formation process of TiO-(B) nanobelts and their sensing properties were investigated in detail. FE-SEM was used to study the surface of the obtained structures.
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April 2022
In this work we have designed and developed a low cost and simple instrument to purify air in an enclosure. The device sucks up the air in the enclosed area, kills the microorganisms and let clean air flow out. A combination of an ultra violet light and an electric field are used to kill the microorganisms in air.
View Article and Find Full Text PDFHerein, we report the catalyst assisted growth of TiO one-dimensional (1D) nanowires (NWs) on alumina substrates by the thermal oxidation technique. RF magnetron sputtering was used to deposit a thin Ti metallic layer on the alumina substrate, followed by an Au catalytic layer on the Ti metallic one. Thermal oxidation was carried out in an oxygen deficient environment.
View Article and Find Full Text PDFAn efficient and simple protocol for synthesis of novel La(2)O(3) hollow nanospheres of size about 30 ± 2 nm using polymeric micelles is reported. The La(2)O(3) hollow nanospheres exhibit high charge capacity and cycling performance in lithium-ion rechargeable batteries (LIBs), which was scrutinized for the first time among the rare-earth oxides.
View Article and Find Full Text PDFNovel lanthanum borate (LaBO(3)) hollow nanospheres of size 34±2 nm have been reported for the first time by soft-template self-assembly process. Poly(styrene-b-acrylic acid-b-ethylene oxide) (PS-PAA-PEO) micelle with core-shell-corona architecture serves as an efficient soft template for fabrication of LaBO(3) hollow particles using sodium borohydride (NaBH(4)) and LaCl(3)⋅7H(2)O as the precursors. In this template, the PS block (core) acts as a template of the void space of hollow particle, the anionic PAA block (shell) serves as reaction field for metal ion interactions, and the PEO block (corona) stabilizes the polymer/lanthana composite particles.
View Article and Find Full Text PDFPolymeric micelles with core-shell-corona architecture have been found to be the efficient colloidal templates for synthesis of periodic organosilica hollow nanospheres over a broad pH range from acidic to alkaline media. In alkaline medium, poly (styrene-b-[3-(methacryloylamino)propyl] trimethylammonium chloride-b-ethylene oxide) (PS-PMAPTAC-PEO) micelles yield benzene-silica hollow nanospheres with molecular scale periodicity of benzene groups in the shell domain of hollow particles. Whereas, an acidic medium (pH 4) produces diverse hollow particles with benzene, ethylene, and a mixture of ethylene and dipropyldisulfide bridging functionalities using poly(styrene-b-2-vinyl pyridine-b-ethylene oxide) (PS-PVP-PEO) micelles.
View Article and Find Full Text PDFWe report a novel protocol to prepare titania hollow nanospheres of size about 28 ± 1 nm with micelles of asymmetric triblock copolymers. The hollow particles exhibit unique electrochemical properties in lithium ion rechargeable batteries such as high capacity, very low irreversible capacity loss, and high cycling performance.
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