A continuous-wave (CW) interband cascade laser (ICL) based mid-infrared sensor system was demonstrated for simultaneous detection of atmospheric methane (CH) and ethane (CH). A 3.337 µm CW ICL with an emitting wavenumber range of 2996.
View Article and Find Full Text PDFA sensor system based on a continuous wave, external-cavity quantum-cascade laser (CW EC-QCL) was demonstrated for simultaneous detection of atmospheric HO, HDO, NO and CH using a compact, dense pattern multi-pass gas cell with an effective path-length of 57.6 m. The EC-QCL with a mode-hop-free spectral range of 1225-1285 cm operating at ~7.
View Article and Find Full Text PDFTwo compact TDLAS sensor systems based on different structural optical cores were developed. The two optical cores combine two recent developments, gallium antimonide (GaSb)-based ICL and a compact multipass gas cell (MPGC) with the goal to create compact TDLAS based sensors for the mid-IR gas detection with high detection sensitivity and low power consumption. The sensors achieved minimum detection limits of ~5 ppbv and ~8 ppbv, respectively, for CH and CH concentration measurements with a 3.
View Article and Find Full Text PDFA continuous wave (CW) quantum cascade laser (QCL) based absorption sensor system was demonstrated and developed for simultaneous detection of atmospheric nitrous oxide (N(2)O), methane (CH(4)), and water vapor (H(2)O). A 7.73-µm CW QCL with its wavelength scanned over a spectral range of 1296.
View Article and Find Full Text PDFA quartz-enhanced photoacoustic absorption spectroscopy (QEPAS)-based gas sensor was developed for methane (CH₄) and nitrous-oxide (N₂O) detection. The QEPAS-based sensor was installed in a mobile laboratory operated by Aerodyne Research, Inc. to perform atmospheric CH₄ and N₂O detection around two urban waste-disposal sites located in the northeastern part of the Greater Houston area, during DISCOVER-AQ, a NASA Earth Venture during September 2013.
View Article and Find Full Text PDFA parallel factor (PARAFAC) analysis approach was used to study the character and composition of dissolved organic matter (DOM) in a multicoagulant (two aluminum-based coagulants) full scale drinking water treatment plant. A three year, long-term assessment was conducted based on deconstruction of the excitation-emission matrices (EEM) of over 1000 water samples collected before and after parallel coagulation treatment basins. Two humic moieties and a protein-like group were identified in the raw and treated waters.
View Article and Find Full Text PDFFluorescence monitoring of the raw and treated water after coagulation-filtration in a drinking water treatment plant in Northeast Ohio was conducted during a period of 32 months. Principal fluorophore groups present in the dissolved organic matter (DOM) of the raw, treated, raw-treated combined water and differential fluorescence data sets comprising over 680 samples were determined through Parallel Factor (PARAFAC) analysis. Four components (two humic-like and two with protein nature) were identified in each model and their degree of similarity was evaluated using the Uncorrected Matrix Correlation (UMC), a measure of spectral overlapping.
View Article and Find Full Text PDF