Two species belonging to the family Neobisiidae are diagnosed, described, and illustrated from China: . from Chongqing Municipality, and Hu & Zhang, 2012 from Fujian Province. The male of is reported for the first time.
View Article and Find Full Text PDFA new sterically hindered "picket fence-like" porphyrin with chelates for the second metal atom, HTImPP (TImPP = meso-tetrakis[α,α,α,α-o-(5-imidazolecarboxylaminophenyl)]porphyrinato), is developed and used in the synthesis of four iron(II) bis(imidazole) derivatives, which are characterized by single crystal X-ray and other spectroscopies. The comprehensive studies on the crystal structures revealed noteworthy features including new axial ligand arrangements, deformed porphyrin planes, and strongly tilted pickets which can be rationalized by analysis of the intra- and intermolecular interactions. Solid-state Mössbauer experiments on [Fe(TImPP)(1-MeIm)] were conducted at several temperatures from 295 to 25 K.
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