Chemometrics assisted dispersive liquid-liquid microextraction for quantification of seven UV filters in urine samples by HPLC-DAD.

In the present study, dispersive liquid-liquid microextraction followed by high performance liquid chromatography-diode array detection has been developed as simple, rapid, accurate, and efficient sample preparation method for simultaneous determination of seven organic UV filters in urine samples. The influence of the main effects as well as their interactions was studied through a 2((6-2)) fractional factorial design. The candidate parameters were: type and volume of dispersant and extraction solvents, sample pH, and salt concentration.

Fast liquid chromatography-diode array detection assisted by chemometrics for quantification of seven ultraviolet filters in effluent wastewater.

A fast chromatographic method is presented for simultaneous quantification of seven organic ultraviolet (UV) filters (benzophenone-3,4-methylbenzilidene camphor, octocrylene, 1-(4-tert-butylphenyl)-3-(4-methyoxyphenyl)1,3-propanedione), ethylhexyl methoxy cinnamate, ethylhexyl salicylate and homosalate) in effluent wastewater samples. The UV filters were pre-concentrated by Bond Elut-ENV cartridges and separated on an ODS column (15 cm × 0.46 cm, 5 μm) in less than 2.