Inducing β Phase Crystallinity in Block Copolymers of Vinylidene Fluoride with Methyl Methacrylate or Styrene.

Block copolymers of poly(vinylidene fluoride) (PVDF) with either styrene or methyl methacrylate (MMA) were synthesized and analyzed with respect to the type of the crystalline phase occurring. PVDF with iodine end groups (PVDF-I) was prepared by iodine transfer polymerization either in solution with supercritical CO₂ or in emulsion. To activate all iodine end groups Mn₂(CO) is employed.