Publications by Nadine R Goetz

Publications by authors named "Nadine R Goetz"

Page 1 of 1

Protonation of nitriles: isolation and characterization of alkyl- and arylnitrilium ions.

Ralf Haiges Amanda F Baxter Nadine R Goetz Joachim A Axhausen Theresa Soltner

Dalton Trans

May 2016

Article Synopsis

The study investigates how various nitriles (like acetonitrile and benzonitrile) react with strong acid mixtures (HF/AsF5 or HF/SbF5) leading to the formation of protonated nitrile compounds.
The resulting protonated products, known as nitrilium ions, were isolated as different salts (e.g., [AsF6](-), [SbF6](-), and [Sb2F11](-)).
These nitrilium ions were analyzed and characterized using techniques such as multinuclear NMR, vibrational spectroscopy, and X-ray crystallography to understand their structural properties.

View Article and Find Full Text PDF

The protonation of HSO(3)F: preparation and characterization of fluorodihydroxyoxosulfonium hexafluoroantimonate [H(2)SO(3)F](+)[SbF(6)](-).

Raphael Seelbinder Nadine R Goetz Johannes Weber Rolf Minkwitz Andreas J Kornath

Chemistry

January 2010

Sulfurtrioxide reacts with the superacidic solutions XF/SbF(5) (X=H, D) to form the corresponding salts [X(2)SO(3)F](+)[SbF(6)](-), which are the protonated forms of fluorosulfuric acid. The salts have been characterized by vibrational spectroscopy and a single-crystal structure analysis. [H(2)SO(3)F](+)[SbF(6)](-) crystallizes in the monoclinic space group P2(1)/n (no.

View Article and Find Full Text PDF