Formation of Ordered Honeycomb-like Structures of Manganese Oxide 2D Nanocrystals with the Birnessite-like Structure and Their Electrocatalytic Properties during Oxygen Evolution Reaction upon Water Splitting in an Alkaline Medium.

In this work, a chemical reaction between gaseous ozone and aqueous solution of Mn(CHCOO) in drops has been researched. It has been shown that the formation of H MnO·nHO nanocrystals with a morphology of nanosheets and a birnessite-like crystal structure with a thickness of 5-8 nm is observed on the surface of drops. These nanocrystals are oriented spontaneously to the solution-gas interface and constitute peculiar ribbons with a width of 1-2 μm, some of which form ordered honeycomb structures (OHS) with a 5-20 μm cell size.