Facile and eco-friendly method of starch nanocrystals esterified with oleic acid using natural clay as a catalyst: Synthesis, Box-Behnken optimization, characterization and analysis of thermal and antioxidant properties.

This study investigates the synthesis of corn starch nanocrystals (SNCs) via sulfuric acid hydrolysis. Esterification of oleic acid (OA) with SNCs was carried out using Maghnite-H as a catalyst, a non-polluting, eco-friendly proton-exchanged montmorillonite-based green catalyst suitable for various chemical processes. Optimization of synthesis parameters, including reaction temperature, duration, and catalyst quantity, was conducted using response surface methodology (RSM) with a central composite design incorporating three factors and three levels.