Efficacy of Fe-Mg-bimetallic biochar in stabilization of multiple heavy metals-contaminated soil and attenuation of toxicity in spinach (Spinacia oleracea L.).

Globally, soil contamination with heavy metals (HMs) pose serious threats to soil health, crop productivity, and human health. The present investigation involved synthesis and analysis of biochar with bimetallic combination of iron and magnesium (Fe-Mg-BC). Our study evaluated how Fe-Mg-BC affects the absorption of cadmium (Cd), lead (Pb), and copper (Cu) in spinach (Spinacia oleracea L.

A critical review on the organo-metal(loid)s pollution in the environment: Distribution, remediation and risk assessment.

Toxic metal(loid)s, e.g., mercury, arsenic, lead, and cadmium are known for several environmental disturbances creating toxicity to humans if accumulated in high quantities.

Enhanced capacity of thiol-functionalized sugarcane bagasse and rice husk biochars for arsenite sorption in aqueous solutions.

The utilization of biowastes for producing biochar to remove potentially toxic elements from water represents an important pathway for aquatic ecosystem decontamination. Here we explored the significance of thiol-functionalization on sugarcane bagasse biochar (Th/SCB-BC) and rice husk biochar (Th/RH-BC) to enhance arsenite (As(III)) removal capacity from water and compared their efficiency with both pristine biochars (SCB-BC and RH-BC). The maximum As(III) sorption was found on Th/SCB-BC and Th/RH-BC (2.

Adsorption-coupled Fenton type reduction of bromate in water by high-yield polymer-derived ceramic-supported nano-zerovalent iron.

Nano-zerovalent iron (nZVI) is a promising material for the removal of both organic and inorganic pollutants from contaminated water. This study investigates the potential of a novel composite of nZVI on a polymer-derived supporting ceramic (nZVI-PDC) synthesized via the liquid-phase reduction method for the simultaneous adsorption and Fenton-type reduction of bromate anion (BrO) in water. The nZVI nanoparticles were effectively anchored onto the PDC by impregnating high-yield carbon in a ferrous sulfate solution.

Super capacity of ligand-engineered biochar for sorption of malachite green dye: key role of functional moieties and mesoporous structure.

This study synthesized a new thiomalic acid-modified rice husk biochar (TMA-BC) as a versatile and eco-friendly sorbent. After undergoing chemical treatments, the mercerized rice husk biochar (NaOH-BC) and TMA-BC samples showed higher BET surface area values of 277.1 m/g and 305.

Evaluation of iron-modified biochar on arsenic accumulation by rice: a pathway to assess human health risk from cooked rice.

Arsenic (As) contamination of rice grain poses a serious threat to human health. Therefore, it is crucial to reduce the bioavailability of As in the soil and its accumulation in rice grains to ensure the safety of food and human health. In this study, mango (Mangifera indica) leaf-derived biochars (MBC) were synthesized and modified with iron (Fe) to produce FeMBC.

Role of organic and inorganic amendments on physiological attributes of germinating pea seedlings under arsenic stress.

There are scarce data regarding the effects of soil amendments on biophysicochemical responses of plants at the early stages of growth/germination. This study critically compares the effects of ethylene-diamine-tetra-acetic-acid (EDTA) and calcium (Ca) on biophysicochemical responses of germinating pea seedlings under varied arsenic levels (As, 25, 125, 250 µM). Arsenic alone enhanced hydrogen peroxide (HO) level in pea roots (176%) and shoot (89%), which significantly reduced seed germination percentage, pigment contents, and growth parameters.

Glyphosate in the environment: interactions and fate in complex soil and water settings, and (phyto) remediation strategies.

Glyphosate (Gly) and its formulations are broad-spectrum herbicides globally used for pre- and post-emergent weed control. Glyphosate has been applied to terrestrial and aquatic ecosystems. Critics have claimed that Gly-treated plants have altered mineral nutrition and increased susceptibility to plant pathogens because of Gly ability to chelate divalent metal cations.

The impact of rainwater-borne HO-induced Fenton process on root iron plaque formation and arsenic accumulation in rice.

Arsenic (As) contamination is a global concern, especially in paddy fields, as it represents a significant pathway for As reaching in the food chain. This is primarily due to the high accumulation of As in rice grains, which is a staple food for billions of people globally. Here we investigated the effect of synthetic rainwater-borne hydrogen peroxide (HO)-induced Fenton oxidation process in paddy soil on As uptake and speciation in rice plants at different growth stages.

Exploring the potential of bacterial-augmented floating treatment wetlands for the remediation of detergent-contaminated water.

Due to industrialization and urbanization, the use of detergents inadvertently led to contamination of aquatic environments, thus posing potential threat to aquatic organisms and human health. One of the main components of detergents is linear alkylbenzene sulfonate (LAS), which can cause toxic effects on living organisms, particularly aquatic life in the environment. In this study, floating treatment wetlands (FTWs) mesocosms were developed and augmented with LAS-degrading bacteria.

Coupled sorptive and oxidative antimony(III) removal by iron-modified biochar: Mechanisms of electron-donating capacity and reactive Fe species.

Sorption and oxidation are two potential pathways for the decontamination of trivalent antimony (Sb(III))-bearing water, using iron (Fe)-modified biochar (FeBC). Here we investigated the sorption and oxidation behavior of FeBC for Sb(III) in aqueous solutions. Results revealed that Sb(III) removal by FeBC was significantly improved showing the maximum Sb(III) sorption (64.

A critical review on the separation of heavy metal(loid)s from the contaminated water using various agricultural wastes.

Wastewater contamination with heavy metal(loids)s has become a worldwide environmental and public health problem due to their toxic and non-degradable nature. Different methods and technologies have been applied for water/wastewater treatment to mitigate heavy metal(loid)-induced toxicity threat to humans. Among various treatment methods, adsorption is considered the most attractive method because of its high ability and efficiency to remove contaminants from wastewater.

The evaluation of bacterial-augmented floating treatment wetlands for concomitant removal of phenol and chromium from contaminated water.

Contamination of aquatic ecosystems with organic and inorganic contaminants is a global threat due to their hazardous effects on the environment and human health. Floating treatment wetland (FTW) technology is a cost-effective and sustainable alternative to existing treatment approaches. It consists of a buoyant mat in which wetland plants can grow and develop their roots in a suspended manner and can be implemented to treat stormwater, municipal wastewater, and industrial effluents.

Unveiling the significance of foliar-applied silicon, selenium and phosphorus for the management and remediation of arsenic in two different rice genotypes.

Under paddy soil conditions, rice plants are vulnerable to arsenic (As) accumulation, thus causing potential threat to human health. Here we investigated the influence of foliar-applied phosphorus (P: 10 and 20 mg L), silicon (Si: 0.6 and 1.

Biochar addition increased soil bacterial diversity and richness: Large-scale evidence of field experiments.

Biochar plays a crucial role in enhancing soil ecological functions and productivity, and mitigating environmental pollution. Despite the available studies conducted through high-throughput sequencing to understand the effects of biochar on soil bacterial diversity and richness, a comprehensive understanding remains elusive. Our global meta-analysis addresses this knowledge gap, incorporating 473 pairs of observations from 84 studies to assess soil bacterial diversity and richness response to biochar addition.

Pandemic COVID-19 ends but soil pollution increases: Impacts and a new approach for risk assessment.

For three years, a large amount of manufactured pollutants such as plastics, antibiotics and disinfectants has been released into the environment due to COVID-19. The accumulation of these pollutants in the environment has exacerbated the damage to the soil system. However, since the epidemic outbreak, the focus of researchers and public attention has consistently been on human health.

Effect of freshwater and wastewater irrigation on buildup of toxic elements in soil and maize crop.

Untreated wastewater is routinely used for agricultural activities in water-stressed regions, thereby causing severe ecological risks by various pollutants. Hence, management strategies are needed to cope with the environmental issues related to wastewater use in agriculture. This pot study evaluates the effect of mixing either freshwater (FW) or groundwater (GW) with sewage water (SW) on the buildup of potentially toxic elements (PTEs) in soil and maize crop.

Biochar/nano-zerovalent zinc-based materials for arsenic removal from contaminated water.

In this study, we explored the potential of a newly prepared nano-zero valent zinc (nZVZn), biochar (BC)/nZVZn and BC/hydroxyapatite-alginate (BC/HA-alginate) composites for the removal of inorganic As species from water. Relatively, higher percentage removal of As(III) and As(V) was obtained by nZVZn at pH 3.4 (96% and 94%, respectively) compared to BC/nZVZn (90% and 88%) and BC/HA-alginate (88% and 80%) at pH 7.

Biowaste-based sorbents for arsenic removal from aqueous medium and risk assessment.

Water contamination by arsenic (As) is widespread and is posing serious health threats globally. Hence, As removal techniques/adsorbents need to be explored to minimize potentials hazards of drinking As-contaminated waters. A column scale sorption experiment was performed to assess the potential of three biosorbents (tea waste, wheat straw and peanut shells) to remove As (50, 100, 200 and 400 µg L) from aqueous medium at a pH range of 5-8.

Accumulation pattern and risk assessment of potentially toxic elements in selected wastewater-irrigated soils and plants in Vehari, Pakistan.

There are scarce data about the accumulation pattern and risk assessment of potentially toxic elements (PTEs) in soil and associated potential ecological risks, especially in less-developed countries. This study aims to assess the pollution levels and potential ecological risks of PTEs (As, Cr, Cd, Cu, Ni, Mn, Pb and Zn) in wastewater-irrigated arable soils and different edible-grown plants in selected areas of Vehari, Pakistan. The results revealed that the values of PTEs in soil samples were higher than their respective limit values by 20% for As, 87% for Cd, 15% for Cu, 2% for Cr, 83% for Mn, 98% for Fe, and 7% for Zn.

Global arsenic dilemma and sustainability.

Arsenic (As) is one of the most prolific natural contaminants in water resources, and hence, it has been recognized as an emerging global problem. Arsenic exposure through food exports and imports, such as As-contaminated rice and cereal-based baby food, is a potential risk worldwide. However, ensuring As-safe drinking water and food for the globe is still not stated explicitly as a right neither in the United Nations' Universal Declaration of Human Rights and the 2030 Sustainable Development Goals (SDGs) nor the global UNESCO priorities.

Distribution and ecological risk assessment of trace elements in the paddy soil-rice ecosystem of Punjab, Pakistan.

Trace elements (TEs) contamination of agricultural soils requires suitable criteria for regulating their toxicity limits in soil and food crops, which depends on their potential ecological risk spanning regional to global scales. However, no comprehensive study is available that links TE concentrations in paddy soil with ecological and human health risks in less developed regions like Pakistan. Here we evaluated the data set to establish standard guidelines for defining the hazard levels of various potentially toxic TEs (such as As, Cd, Co, Cu, Cr, Fe, Mn, Ni, Pb, Se, Zn) in agricultural paddy soils of Punjab, Pakistan.

Modified and pristine biochars for remediation of chromium contamination in soil and aquatic systems.

Chromium (Cr) contamination in soil and water poses high toxicity risks to organisms and threatens food and water security worldwide. Biochar has emerged as a promising material for cleaning up Cr contamination owing to biochar's strong capacity to immobilize Cr. This paper synthesizes information on biochar modification for the efficient remediation of Cr contamination in soil and water, and critically reviews mechanisms of Cr adsorption on pristine and modified biochars.

The significance of eighteen rice genotypes on arsenic accumulation, physiological response and potential health risk.

Rice is an important food crop that is susceptible to arsenic (As) contamination under paddy soil conditions depending on As uptake characteristics of the rice genotypes. Here we unveiled the significance of eighteen (fine and coarse) rice genotypes against As accumulation/tolerance, morphological and physiological response, and antioxidant enzymes-enabled defense pathways. Arsenic significantly affected rice plant morphological and physiological attributes, with relatively more impacts on fine compared to coarse genotypes.