Fungal mycelium is emerging as a source for sustainable bio-based materials. Fungal biomass of Aspergillus oryzae was prepared by cultivation on bread waste hydrolysate to valorize this abundant food waste. Chitin-glucan-rich alkali-insoluble material (AIM) was isolated from fungal biomass, formed into hydrogels, and wet spun into monofilaments.
View Article and Find Full Text PDFA green strategy that significantly accelerates the biodegradation rate of cellulose acetate (CA) by triggering deacetylation was demonstrated. Lipase isolated from was immobilized on CA particles (immobilized lipase (IL)) by a physical entrapment method and further incorporated in CA films. After 40 days of aging in contact with external enzymes (lipase and cellulase), the number-average molecular weight () of CA/IL 5% decreased by 88%, while the of CA only exhibited a 48% reduction.
View Article and Find Full Text PDFAn environmentally friendly non-woven nanotextile has been prepared using enantiomeric pairs of poly (lactic acid) PLA by electrospinning technique. Solution blending of synthesized high molecular weight (⁓10 Da) poly (L-lactic acid) PLLA and poly (D-lactic acid), PDLA for prolonged time stirring produce solely stereocrystallites (sc). The high crosslinking effect of sc-PLA has played an important role, with multifunctional behaviour on the addition of anatase-TiO (a-TiO) in three different ways (Case-I-III).
View Article and Find Full Text PDFThis study endeavoured to explore and fabricate antiviral and antibacterial facemasks using zinc (oligo-lactate) (ZL), developed through a microwave synthesis technique. The prepared nano-fabric layer has excellent antiviral and antibacterial properties against Newcastle Disease Virus (NDV) and and , respectively. Thermogravimetric analysis (TGA) of ZL shows a two-step thermal degradation, which confirms the formation of low molecular weight end group lactyl units with zinc ions.
View Article and Find Full Text PDFThe current study evaluates aerobic biodegradation of melt extruded poly(lactic acid) PLA based blends under composting conditions. Samples of neat PLA (NPLA) and bio-based polyblend composites of PLA/LLDPE (linear low-density polyethylene) having different concentration of MCC (microcrystalline cellulose crystal) were analyzed to understand the biodegradation behavior of these blends under simulated composting conditions. Biodegradation kinetics revealed that higher content of MCC and PLA accelerated the biodegradation process of the polymeric blends.
View Article and Find Full Text PDFThe present study evaluates biodegradation of the polyblends of poly(lactic acid) (PLA), polycaprolactone (PCL) and microcrystalline cellulose (MCC) in different compositions and comparison of the properties of those blends with that of neat PLA and neat PCL. The samples were melt extruded and blended to evaluate the environmental fate of the polyblends under simulated composting conditions following the standard ASTM International D5338-15 protocol. It was seen that blends with a higher concentration of PCL and MCC in the PLA matrix showed higher carbon mineralization percentage in comparison to the blends having low PCL and MCC components.
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