Cage-catenanes are chemical constructs where two or more cage-like molecules or assemblies are mechanically interlocked together. We report a new class of cage-catenanes where dimeric metal-organic cage-catenanes are linked into larger assemblies through additional bridging metal chloride links. These crystalline materials are obtained from the reaction of tris(nicotinoyl)cyclotriguaiacylene (L1) with Cu(II) salts, and all feature a tetramer of cages where two {Cu(L1)(X)} cages (X=anion) are mechanically interlocked, and link to each other and to another {Cu(L1)(X)} cage-catenane through a planar, linear tetranuclear {Cu(μ-Cl)Cl} cluster.
View Article and Find Full Text PDFTwo new species Richtersia japonica sp. nov. and Richtersia amurica sp.
View Article and Find Full Text PDFDespite a long period of application of metal implants, carbon-carbon medical composites are also widely used for bone defect prosthesis in surgery, dentistry, and oncology. Such implants might demonstrate excellent mechanical properties, but their biocompatibility and integration efficiency into the host should be improved. As a method of enhancing, the electrophoretic deposition of fine-dispersed hydroxyapatite (HAp) on porous carbon substrates might be recommended.
View Article and Find Full Text PDFThe economic condition, national economic significance and prospects for the development of sheep breeding in our country directly depend on the meat productivity of sheep. The purpose of our research was to study the qualitative indicators of sheepskins and the histological structure of the skin of Kalmyk fat-tailed rams and crossbreeds obtained on the basis of crossing of Kalmyk fat-tailed ewes with Dorper rams. The work was carried out in LLC "Agrofirma Aduchi", Republic of Kalmykia.
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