Photochemistry of the Fe(III)-iminodiacetic acid complex under UVA and UV/Vis irradiation: synthesis and characterisation.

The photochemistry of Fe(III)-Iminodiacetic acid complex (Fe(III)-IDA) was studied under UVA and UV/Vis irradiation. The synthesis was realised via molar ratio method modified by reaction of IDA as ligand with Fe(III) as metal. The interaction of Fe(III) with IDA was characterised using Fourier-transform infrared (FTIR) and spectroscopy UV-visible.

Enhanced degradation of 2,6-dimethylphenol by photocatalytic systems using TiO assisted with HO and Fe(III).

In this study, several photocatalytic degradation systems were investigated using 2,6-dimethylphenol (2,6-DMP) as a model compound. Highly reactive species are formed in four systems, Fe(III), TiO, TiO/HO and TiO/Fe(III) where complete degradation of 2,6-DMP was achieved under UV radiation. Photodegradation of the 2,6-DMP has been described by pseudo-first order kinetic model in the presence of TiO.

Effect of Fe(III)-bicarboxylic complexes in removal pollutant under UV and sunlight in aqueous solutions.

In this study, we have applied Fe(III)-bi-carboxylic acid solutions containing citrate and oxalate ligands to degrade 3-méthylphénol (3MP) in aqueous solutions both under UV and sunlight. Under irradiation at 365 nm, the photodegradation of 3MP is markedly better in the presence of the Fe(III)Ox complex than in the Fe(III)Cit complex this fact is explained by an excess of HO and Fe(II) generated by Fe(III)Ox photolysis creating the Fenton process. We mixtures were realized by varying the composition of the Fe(III)Cit and Fe(III)Ox in order to see the additives of the degradation efficiency of the pollutant.

Use of oxalic acid as inducer in photocatalytic oxidation of cresol red in aqueous solution under natural and artificial light.

This work was carried out in the field of water treatment using advanced oxidation processes (AOPs), especially photolysis of carboxylic acid that leads to the formation in situ of hydroxyl radical (·OH). Cresol red (CR) degradation induced by organic acids/UV system was investigated in aqueous solution. The preliminary study of CR-organic acid mixture in the dark and at room temperature allowed confirming the absence of interaction under our experimental conditions.