Triptycene as a scaffold in metallocene catalyzed olefin polymerization.

A set of metallocene olefin polymerization catalysts bearing triptycene moieties in either position 4-5 (complexes Ty1-Ty5) or in position 5-6 (complexes Ty6-Ty8) of the basic dimethylsilyl-bridged bis(indenyl) system has been tested in propene polymerization and in ethene/1-hexene copolymerization. Comparison of the results with QSPR (quantitative structure-property relationship) predictions not parametrized for these exotic ligand variations demonstrates that trends can still be identified by extrapolation. Interestingly, Ty7, upon suitable activation, provides a highly isotactic polypropylene with an exceptional amount of 2,1 regio-errors (8%).

TruEst: a better estimator of evolutionary distance under the INFER model.

Genome rearrangements are evolutionary events that shuffle genomic architectures. The number of genome rearrangements that happened between two genomes is often used as the evolutionary distance between these species. This number is often estimated as the minimum number of genome rearrangements required to transform one genome into another which are only reliable for closely-related genomes.

Chromosome-level genome assembly, annotation, and phylogenomics of the gooseneck barnacle Pollicipes pollicipes.

Background: The barnacles are a group of >2,000 species that have fascinated biologists, including Darwin, for centuries. Their lifestyles are extremely diverse, from free-swimming larvae to sessile adults, and even root-like endoparasites. Barnacles also cause hundreds of millions of dollars of losses annually due to biofouling.

PaReBrick: PArallel REarrangements and BReaks identification toolkit.

Motivation: High plasticity of bacterial genomes is provided by numerous mechanisms including horizontal gene transfer and recombination via numerous flanking repeats. Genome rearrangements such as inversions, deletions, insertions and duplications may independently occur in different strains, providing parallel adaptation or phenotypic diversity. Specifically, such rearrangements might be responsible for virulence, antibiotic resistance and antigenic variation.

High Rates of Genome Rearrangements and Pathogenicity of spp.

are pathogens originating within the lineage but frequently classified as a separate genus. genomes contain numerous insertion sequences (ISs) that lead to pseudogenisation of affected genes and an increase of non-homologous recombination. Here, we study 414 genomes of and strains to assess the contribution of genomic rearrangements to evolution.