Simultaneous injection-effective mixing analysis of palladium.

A novel concept of simultaneous injection-effective mixing analysis (SIEMA) is proposed, and a SIEMA method applied to the spectrophotometric determination of palladium using a water-soluble chromogenic reagent has been demonstrated. The flow configuration of SIEMA is a hybrid format of flow injection analysis (FIA), sequential injection analysis (SIA) and multicommutation in flow-based analysis. Sample and reagent solutions are aspirated into each holding coil through each solenoid valve by a syringe pump, and then the zones are simultaneously dispensed (injected) into a mixing coil by reversed flow toward a detector through a confluence point.

Determination of nitrite and nitrate in water samples by an automated hydrodynamic sequential injection method.

An automated hydrodynamic sequential injection (HSI) system with spectrophotometric detection was developed. Thanks to the hydrodynamic injection principle, simple devices can be used for introducing reproducible microliter volumes of both sample and reagent into the flow channel to form stacked zones in a similar fashion to those in a sequential injection system. The zones were then pushed to the detector and a peak profile was recorded.

Sequential injection with lab-at-valve (LAV) approach for potentiometric determination of chloride.

Sequential injection with "Lab-at-Valve (LAV)" approach is demonstrated for potentiometric determination of chloride. The LAV flow-through electrode system consists of two Ag/AgCl electrodes: one as a reference electrode, silver chloride activated surface-silver wire soaked in a constant-concentration chloride ion solution in a small tube covered with a polymer-membrane, another as a working electrode (a similar silver chloride activated surface-silver wire) placed in a flow channel. The electrode system is attached at one port of a 10 port multiposition valve.

A dynamic liquid-liquid interfacial pressure detector for the rapid analysis of surfactants in a flowing organic liquid.

Design and development of a dynamic interfacial pressure detector (DIPD) is reported. The DIPD measures the differential pressure as a function of time across the liquid-liquid interface of organic liquid drops (i.e.

Sequential injection analysis with dynamic surface tension detection High throughput analysis of the interfacial properties of surface-active samples.

A sequential injection analysis (SIA) system is coupled with dynamic surface tension detection (DSTD) for the purpose of studying the interfacial properties of surface-active samples. DSTD is a novel analyzer based upon a growing drop method, utilizing a pressure sensor measurement of drop pressure. The pressure signal depends on the surface tension properties of sample solution drops that grow and detach at the end of a capillary tip.