Distributed Acoustic Sensing for Future Planetary Applications: Initial Results From the San Francisco Volcanic Field, a Lunar Analogue.

Seismic imaging is one of the most powerful tools available for constraining the internal structure and composition of planetary bodies as well as enabling our understanding planetary evolution, geology, and distribution of natural resources. However, traditional seismic instrumentation can be heavy and voluminous, expensive, and/or difficult to rapidly deploy in large numbers. Distributed acoustic sensing (DAS) provides a promising new alternative given the ease of deployment, light weight and simplicity of fiber optic cables.

Neighboring Catalytic Sites Are Essential for Electrochemical Dechlorination of 2-Chlorophenol.

The electrocatalytic reduction process is a promising technology for decomposing chlorinated organic pollutants in water but is limited by the lack of low-cost catalysts that can achieve high activity and selectivity. In studying electrochemical dechlorination of 2-chlorophenol (2-CP) in aqueous media, we find that cobalt phthalocyanine molecules supported on carbon nanotubes (CoPc/CNT), which is a highly effective electrocatalyst for breaking the aliphatic C-Cl bonds in 1,2-dichloroethane (DCA) and trichloroethylene (TCE), are completely inactive for reducing the aromatic C-Cl bond in 2-CP. Detailed mechanistic investigation, including volcano plot correlation between dechlorination rate and atomic hydrogen adsorption energy on various transition metal surfaces, kinetic measurements, in situ Raman spectroscopy, and density functional theory calculations, reveals that the reduction of the aromatic C-Cl bond in 2-CP goes through a hydrodechlorination mechanism featuring a bimolecular reaction between adsorbed atomic hydrogen and 2-CP on the catalyst surface, which requires neighboring catalytic sites, whereas the aliphatic C-Cl bonds in DCA and TCE are cleaved by direct electron transfer from the catalyst, which can occur on isolated single sites.

Community Level Correlates of COVID-19 Booster Vaccine Hesitancy in the United States: A Cross-Sectional Analysis.

: Evidence exists that individual-level sociodemographic factors contribute to vaccine hesitancy, but it is unknown how community-level factors affect COVID-19 booster dose hesitancy. The current study aims to fill this knowledge gap by comparing data from a nationwide survey on COVID-19 vaccine hesitancy with a community-level indicator, i.e.

TrhA, a bacterial progestin and adiponectin receptor homolog, couples membrane energetics homeostasis and unsaturated fatty acid metabolism.

Members of the widely conserved progestin and adipoQ receptor (PAQR) family function to maintain membrane homeostasis: membrane fluidity and fatty acid composition in eukaryotes and membrane energetics and fatty acid composition in bacteria. All PAQRs consist of a core seven transmembrane domain structure and five conserved amino acids (three histidines, one serine, and one aspartic acid) predicted to form a hydrolase-like catalytic site. PAQR homologs in Bacteria (called TrhA, for transmembrane homeostasis protein A) maintain homeostasis of membrane charge gradients, like the membrane potential and proton gradient that comprise the proton motive force, but their molecular mechanisms are not yet understood.

Broad fault zones enable deep fluid transport and limit earthquake magnitudes.

Constraining the controlling factors of fault rupture is fundamentally important. Fluids influence earthquake locations and magnitudes, although the exact pathways through the lithosphere are not well-known. Ocean transform faults are ideal for studying faults and fluid pathways given their relative simplicity.