The potential to introduce tunable electrical conductivity and molecular magnetism through carrier doping in metal-organic coordination polymers is particularly promising for nanoelectronics applications. Precise control of the doping level is essential for determining the electronic and magnetic properties. In this study, we present a series of one-dimensional coordination polymers, {(HNEt)[CuCo(L)]} (HNEt = triethylammonium, L = 1,2,4,5-tetrakis(methanesulfonamido)benzene), doped with diamagnetic Cu carriers.
View Article and Find Full Text PDFMetal compounds with = 1/2 coordination-frameworks have been emerging as new powerful qubit candidates. In this study, we have reported the CN-based coordination framework TMA[KCoFe(CN)] to be a qubit. We explored the magnetization dynamics and spin coherence of the magnetic dilution of the = 1/2 Fe(III) complex TMA[KFe(CN)] (TMA = tetramethylammonium) in its Co(III)-based diamagnetic analogue TMA[KCo(CN)].
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