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View Article and Find Full Text PDFHighly crystallized Co and CoO nanoparticles embedded in an N-doped amorphous carbon matrix have been successfully fabricated by the molten-salt-assisted method using KClO and zeolitic imidazolate framework-12 (ZIF-12). Pyrolysis of ZIF-12 with different concentrations of KClO leads to embedded Co and CoO nanoparticles in a conductive amorphous carbon network. The impact of salt concentration on the morphology and electrochemical performance of these composites was investigated for electrochemical sensor applications.
View Article and Find Full Text PDFIn this work, we report a study examining how different salt concentrations affect the structure and electrochemical performance of two CoO/C materials designed for the fabrication of an easy, cheap, fast, safe, and useful electrochemical sensor for the detection of Palbociclib (PLB). CoO nanoparticles were successfully created by encapsulating them in N-doped amorphous carbon matrices by using the molten salt-assisted approach. In this process, different amounts of potassium iodate and zeolitic imidazolate framework-12 (ZIF-12) were used, followed by pyrolysis at 800 °C.
View Article and Find Full Text PDFA sophisticated electrochemical sensor is presented employing a glassy carbon electrode (GCE) modified with a novel composite of synthesized graphitic carbon nitride (g-CN) and CoNiO bimetallic oxide nanoparticles (g-CN/CoNiO). The sensor's electrocatalytic capabilities for Sunitinib (SUNI) oxidation were demonstrated exceptional performance with a calculated detection limit (LOD) of 52.0 nM.
View Article and Find Full Text PDFIn the current study, we report the synthesis of a novel composite material composed of banana peel activated carbon (BPAC), nickel iron oxide (NiFeO), and manganese cobalt iron layered double hydroxide (MnCoFe-LDH) to create a high-performance electrochemical sensor to detect Palbociclib (PLB). The composite was successfully immobilized on a glassy carbon electrode (GCE) surface to create a modified electrode. The performance of the electrode was thoroughly evaluated, considering parameters such as electroactive surface areas (ESA), electron transfer rate constant (k), and exchange current density (j).
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