Carbon determination in carbon-manganese steels under atmospheric conditions by Laser-Induced Breakdown Spectroscopy.

The most sensitive lines of carbon, used nowadays for its determination in steels by laser-induced-breakdown spectroscopy (LIBS), are at vacuum UV and, thereby, LIBS potential is significantly reduced. We suggested the use of the C I 833.51 nm line for carbon determination in low-alloy steels (c(C)~0.

Reduction of the matrix influence on analytical signal in laser-enhanced ionization spectrometry with laser sampling.

The novel approach using a slope of correlation line (laser-enhanced ionization of lithium versus laser-induced plasma emission of aluminum) as analytical signal was proposed for reduction of matrix interferences in laser-enhanced ionization spectrometric determination of Li with laser sampling.

Determination of alkali metals by laser-induced atomic-ionization in flames.

The technique of laser-induced atomic-ionization (AI) in flames has been used for direct determination of Na, K, Rb, and Cs in samples such as water, high-purity alkali metals and their salts and polymeric organosilicon compounds. Different procedures for sample introduction into the flame were studied: (a) the sample was placed onto the cathode of the detector (this gave limits of detection for Na and Cs of 4 x 10(-16) and 2 x 10(-15) g, respectively), (b) electrothermal vaporization and (c) aspiration of the sample into the flame. To reduce the interference of SiO(2) in the AI determination of K in polymeric organosilicon compounds (at the level of 10(-3)-10(-5)%), a procedure involved additional electrical heating of the FID cathode was developed.

Laser atomic-ionization determination of caesium in flames.

The laser atomic-ionization (AI) method has been developed for determination of caesium in flames. The limit of detection for caesium in pure aqueous solution is 4 pg ml . The interference of Li, Na, K, Rb, Ca and Fe with the AI signal of caesium has been investigated and explained.

Intracavity spectroscopy with a photon detector based on stepwise atom photo-ionization.

A method of measuring atomic-absorption factors by means of a photon detector based on stepwise atom photo-ionization is proposed for the first time. This method can be widely used in laser analytical spectroscopy.