Potential Crown Discoloration Induced by the Combination of Various Intracanal Medicaments and Scaffolds Applied in Regenerative Endodontic Therapy.

Background: Regenerative endodontics involves the use of various root canal medicaments and scaffolds, which may cause crown discoloration.

Aim: This study aimed to investigate the combined crown discoloration of scaffolds [platelet-rich fibrin (PRF) and blood clot] applied after administration of different medicaments [modified triple antibiotic paste including doxycycline (mTAPd), modified double antibiotic paste (mDAP), calcium hydroxide (CH), and propolis].

Methods: In total, 100 human mandibular premolar teeth were selected and prepared.

Development of super nanoantimicrobials combining AgCl, tetracycline and benzalkonium chloride.

In this work, we demonstrate that a simple argentometric titration is a scalable, fast, green and robust approach for producing AgCl/antibiotic hybrid antimicrobial materials. We titrated AgNO into tetracycline hydrochloride (TCH) aqueous solution, thus forming AgCl/TCH in a one-step procedure. Furthermore, we investigated the one-pot synthesis of triply synergistic super-nanoantimicrobials, combining an inorganic source of Ag ions (AgCl), a disinfecting agent (benzyl-dimethyl-hexadecyl-ammonium chloride, BAC) and a molecular antibiotic (tetracycline hydrochloride, TCH).

Investigation on Gold Dissolution Performance and Mechanism in Imidazolium Cyanate Ionic Liquids.

To explore green gold leaching reagents, a series of imidazolium cyanate ionic liquids (ILs), 1-ethyl-3-methyl-imidazolium cyanate ([CMIM][OCN]), 1-propyl-3-methyl-imidazolium cyanate ([CMIM][OCN]) and 1-butyl-3-methyl-imidazolcyanate ([CMIM][OCN]) were synthesized and characterized by Nuclear Magnetic Resonance (NMR), Fourier Transform Infrared Spectroscopy (FTIR) and thermogravimetric (TG) analysis. In this research, the imidazolium cyanates were utilized as a solute, which not only decreased the usage of ILs but also increased their gold dissolution capability. The gold dissolution performances of three imidazolium cyanates were characterized by dynamic leaching test and Scanning Electron Microscopy (SEM).

Molecular dynamics simulations of the solubility and conformation change of chitosan grafted polyacrylamide: Impact of grafting rate.

Graft modification is an effective approach to improve the water solubility and molecular weight of chitosan. This work investigated the effect of grafting rate on water solubility of chitosan-grafted polyacrylamide (Chi-g-PAM) using molecular dynamics simulations. The intramolecular and intermolecular interaction between Chi-g-PAM with the grafting rate of 100%-250% and water together with the conformation change were analyzed by radial distribution function (RDF), radius of gyration, solvation free energy (ΔG), mean square displacement, diffusion coefficient and shear viscosity.