Fabrication of a new type of organic-inorganic hybrid superlattice films combined with titanium oxide and polydiacetylene.

We fabricated a new organic-inorganic hybrid superlattice film using molecular layer deposition [MLD] combined with atomic layer deposition [ALD]. In the molecular layer deposition process, polydiacetylene [PDA] layers were grown by repeated sequential adsorption of titanium tetrachloride and 2,4-hexadiyne-1,6-diol with ultraviolet polymerization under a substrate temperature of 100°C. Titanium oxide [TiO2] inorganic layers were deposited at the same temperatures with alternating surface-saturating reactions of titanium tetrachloride and water.

Large scale synthesis and enhanced field emission properties from hybrid CuO/ZnO nanorod.

Upper-directionally grown nanorods were synthesized on a large scale by a simple method of direct heating of Cu foil in air. Hybrid CuO/ZnO nanorods were fabricated by ZnO thin film coating using magnetron sputtering. Field emission (FE) measurements of CuO and hybrid CuO/ZnO nanorod films show that they have turn-on field of 3.