Insecticides pose hazardous environmental effects and can enter the food chain and contaminate water resources. Ionic liquids (ILs) have recently drawn much interest as environmentally friendly solvents and have been an efficient choice for extracting pesticides because of their outstanding thermophysical characteristics and tunable nature. In this study, ILs were screened using COSMO-RS (Conductor-like Screening Model for Real Solvents) to extract organochlorine insecticides from water at 289 K.
View Article and Find Full Text PDFAddressing the critical issue of water pollution, this review article emphasizes the need to remove hazardous dyes and phenolic compounds from wastewater. These pollutants pose severe risks due to their toxic, mutagenic, and carcinogenic properties. The study explores various techniques for the remediation of organic contaminants from wastewater, including an enzymatic approach.
View Article and Find Full Text PDFDrilling fluids, commonly referred to as drilling mud, are pumped into the wellbore to expedite the drilling process by moving drilling cuttings to the surface, suspending cuttings, controlling pressure, stabilizing exposed rock, and providing buoyancy, cooling, and lubrication. Understanding the settling of drilling cuttings in base fluids is crucial for successfully mixing drilling fluid additives. In this study, the response surface method Box-Benhken design (BBD) is used to analyze the terminal velocity of the drilling cuttings in a polymeric base fluid of carboxymethyl cellulose (CMC).
View Article and Find Full Text PDFThis study aims to prepare an ion-imprinted polymer (IIP) using copper sulfate as a template and potassium persulfate as an initiator to selectively adsorb copper ions (Cu) from aqueous solutions and in an attempt to also test its applicability for removing strontium ions (Sr). The prepared polymer was denoted by IIP-Cu. Various physical and chemical characterizations were performed for the prepared IIP-Cu.
View Article and Find Full Text PDFIn this study, three types of adsorbents were used to remove and recover strontium ions (Sr) from aqueous and brine solution of seawater reverse osmosis (SWRO), namely roasted date pits (RDP) and RDP modified using copper and nickel salts of potassium hexacyanoferrates to obtain RDP-FC-Cu, and RDP-FC-Ni, respectively. Additionally, the influence of various parameters, including pH, temperature, initial concentration, and co-existing ions was also evaluated. The results revealed that pH 10 was the optimum pH in which the maximum Sr ions were adsorbed.
View Article and Find Full Text PDFThe calcium carbonate (CaCO) scale is one of the most common oilfield scales and oil and gas production bane. CaCO scale can lead to a sudden halt in production or, worst-case scenario, accidents; therefore, CaCO scale formation prevention is essential for the oil and gas industry. Scale inhibitors are chemicals that can mitigate this problem.
View Article and Find Full Text PDFIn this paper, novel composite materials from modified roasted date pits using ferrocyanides were developed and investigated for the recovery of lithium ions (Li) from seawater reverse osmosis (RO) brine. Two composite materials were prepared from roasted date pits (RDP) as supporting material, namely potassium copper hexacyanoferrate-date pits composite (RDP-FC-Cu), and potassium nickel hexacyanoferrate-date pits composite (RDP-FC-Ni). The physiochemical characterization of the RO brine revealed that it contained a variety of metals and salts such as strontium, zinc, lithium, and sodium chlorides.
View Article and Find Full Text PDFFibers are extensively used as a fluid additive in the oil and gas industry to improve hole-cleaning performance, control fluid filtration loss, and enhance hydraulic fracturing effectiveness. Generally, a small amount of fiber is dispersed in the base fluid to achieve the desired results without increasing the viscosity of the base fluid. Nevertheless, sustaining a uniform fiber dispersion can be challenging under wellbore conditions, which is essential for fibers' functionality.
View Article and Find Full Text PDFIn this study, municipal solid waste bottom ash (MSW-BA) and fly ash (MSW-FA) were used as a source of aluminosilicate to prepare geopolymer (GEO) adsorbents (GEO-MSWBA and GEO-MSWFA) for the removal of methylene blue (MB) from water. The effects of temperature, pH, and initial concentration on the MB adsorption onto GEO-MSWBA and GEO-MSWFA were evaluated. The adsorption isotherms parameters and thermodynamics were also determined.
View Article and Find Full Text PDFIncineration has emerged as one of the acceptable ways to treat municipal solid waste (MSW) due to its potential in reducing the mass and volume of the waste. However, it produces two major by-product residues, namely MSW-bottom ash (MSW-BA) and MSW-fly ash (MSW-FA). These residues have gained great attention to their hazardous nature and potential to be reused and recycled.
View Article and Find Full Text PDFExcessive water production from natural gas reservoirs is a main challenge facing the industry nowadays. Polymeric gelants have been widely applied to seal the water production zones, leading to a more feasible production operation. Nevertheless, conventional treatments fail in reservoirs characterized with the presence of sour gases.
View Article and Find Full Text PDFThe rheological characterization for a series of Malic Acid based Hydrogen Bond Donor Natural Deep Eutectic Solvents (NADES) is studied in this work for their potential usage as sorbents for CO capture. Three different NADES combinations were synthesized based on B-Alanine, Betaine and Choline Chloride as Hydrogen Bond Acceptors. The work provides insights on the rheological behaviors of Malic Acid-based NADES at temperature ranges from 25 to 105 °C and shear rates from 0.
View Article and Find Full Text PDFOver the past 5-10 years it has become apparent that the significant energy benefit provided by forward osmosis (FO) for desalination arises only when direct recovery of the permeate product from the solution used to transfer the water through the membrane (the draw solution) is obviated. These circumstances occur specifically when wastewater purification is combined with saline water desalination. It has been suggested that, for such an "open loop" system, the FO technology offers a lower-cost water reclamation option than the conventional process based on reverse osmosis (RO).
View Article and Find Full Text PDFImprovement of sludge dewaterability is greatly hindered by the presence of large amounts of interstitial water molecules trapped in the sludge as a result of strong hydrophilic characteristics. This study has investigated the influence of six different polyacrylamide (PAM) flocculants with different molecular architecture (linear, slightly and highly branched), charge density (CD) and molecular weight (MW) on the electro-kinetics and dewatering of highly stable industrial membrane bioreactor (MBR) sludge. The impact of PAM on flocculation is manifested in the supernatant turbidity, particle zeta potential, sludge capillary suction time (CST), floc size and settleability.
View Article and Find Full Text PDFThe aqueous dispersions of a special type of carbon black (CB) in 1 M lithium bis(trifluoromethanesulfonimide) electrolyte is mainly controlled by the affinity of the aqueous electrolyte towards the CB particles rather than the particle size. In spite of its small particle size (30 nm), this type of CB forms a three-dimensional open network which is rheologically and electrically percolated at a relatively high threshold (2.0 wt%) with enhanced rheological and electrical properties.
View Article and Find Full Text PDFThe aim of this research was to investigate the potential of raw and iron oxide impregnated carbon nanotubes (CNTs) as adsorbents for the removal of selenium (Se) ions from wastewater. The original and modified CNTs with different loadings of FeO nanoparticles were characterized using high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), X-ray diffractometer (XRD), Brunauer, Emmett, and Teller (BET) surface area analyzer, thermogravimetric analysis (TGA), zeta potential, and energy dispersive X-ray spectroscopy (EDS). The adsorption parameters of the selenium ions from water using raw CNTs and iron oxide impregnated carbon nanotubes (CNT-FeO) were optimized.
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