Design of luminescent complexes with different CuI cores based on pyridyl phenoxarsines.

A series of luminescent CuI clusters with stair-step, cubane, and octahedral geometries supported by a novel type of cyclic As,N-ligand, pyridyl-containing 10-phenoxarsines, were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. An unusual arrangement of As,N-bidentate and μ-iodo ligands was found in the octahedral cluster. The structural diversity of the Cu(I) complexes is reflected in their photophysical properties: the phosphorescence spectra of the compounds display emission in a broad spectral range of 495-597 nm.

Luminescent CuI-cubane clusters based on -methyl-5,10-dihydrophenarsazines.

Two luminescent CuI-cubane tetramers with -methyl-10-(-halogenophenyl)-5,10-dihydrophenarsazine ligands were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. The UV-Vis absorption and emission properties were studied and rationalized by DFT and time-dependent DFT calculations. The luminescence behavior was found to be rather different from that of recently reported tetranuclear copper iodide cubane clusters based on As,O-analogues - 10-(aryl)phenoxarsines.

Platinum(II) Complexes with 10-(Aryl)phenoxarsines: Synthesis, Cis/Trans Isomerization, and Luminescence.

Synthesis and structural and photophysical characterization of platinum dihalogenide complexes formulated as [PtHalL], where Hal = Cl and I, with different 10-(aryl)phenoxarsine ligands such as 10-(-chlorophenyl)phenoxarsine, 10-(-tolyl)phenoxarsine, and 10-(phenyl)phenoxarsine are reported. The structures of complexes were determined by NMR spectroscopy, mass spectrometry, and X-ray analysis. Cis/trans isomerism of the complexes in solution was studied by NMR spectroscopy.

[Self-expanding nitinol stents for bleeding from esophageal varices in patients with portal hypertension].

Blakemore probe-obturator was previously preferable for primary hemostasis in patients with bleeding from esophageal varices. Currently, Danis self-expanding nitinol stent became an effective alternative. According to some manufacturers, Danis stent has some advantages over balloon tamponade.

CuI-cubane clusters based on 10-(aryl)phenoxarsines and their luminescence.

In this work, we present the synthesis, structural and photophysical characterization, and theoretical study of tetranuclear copper(i) cubane-type Cu4I4 clusters 6-10 with different 10-(aryl)phenoxarsine ligands - 10-(p-fluorophenyl)phenoxarsine (1), 10-(p-ethoxyphenyl)phenoxarsine (2), 10-(phenyl)phenoxarsine (3), 10-(m-fluorophenyl)phenoxarsine (4), and 10-(o-methoxyphenyl)phenoxarsine (5), respectively. The structures of 1-5 were confirmed by NMR spectroscopy, mass spectrometry, elemental analysis and for complexes 6, 7, and 10 by single-crystal X-ray diffraction analysis. The UV/Vis absorption and emission properties were studied and rationalized by DFT and time-dependent DFT calculations.

Synthesis of 2-d-acrylamide.

2-d-Acrylamide was synthesized via the 2-step procedure starting from acrylonitrile and deuterium oxide. This procedure affords 2-d-acrylamide in 99.9% chemical purity and 98.

[Factors influencing the detection of ischemic stroke in neuroimaging].

Aim: To determine the detectability of foci of acute ischemic stroke (AI) using neuroimaging methods depending on the localization, timing and severity of stroke.

Material And Methods: A retrospective evaluation of 100 case histories of patients hospitalized for ischemic stroke (IS) with determination of the timing of neuroimaging study, fibrinogen level, glucose, INR, NIHSS scores on admission to the hospital, assessment of stroke localization (hemispheric or brainstem), the severity of atherosclerosis of the brachiocephalic arteries (BCA) and presence of atrial fibrillation (AF) was performed. During the stay in the hospital, 54 patients were re-examined to clarify the diagnosis.

[Pathogenesis of the vascular consequences caused by cervical instability and their algorithm for pharmacotherapy].

256 patients with radiologic detected cervical instability were examined. This pathology may be the cause of arterial or venous vertebra-basilar disorders. We realized extensive examination the patients with the cervical instability for the pathogenic correction of vascular consequences.

[Monitoring and assessment contamination of toxic elements food in Tatarstan monitoring and evaluation of contamination by toxic elements of food products in the territory of the Republic of Tatarstan].

Actual consumption of toxic elements in the body of an adult human in the Republic of Tatarstan (during the period of the study of the production in 2008-2012) amounts for lead: 0.68 mg/week for cadmium: 0.18 mg/day, arsenic: 0.

[The effect of the instability of cervical spine on the hemodynamics in the vertebrobasilar system].

256 patients with cephalgia were examined. The main cephalgia cause was a cervical instability. We showed importance of extended examinations for cephalgia pathogenesis.

Bis-phosphonium salts of pyridoxine: the relationship between structure and antibacterial activity.

A series of 23 novel bis-phosphonium salts based on pyridoxine were synthesized and their antibacterial activities were evaluated in vitro. All compounds were inactive against gram-negative bacteria and exhibited the structure-dependent activity against gram-positive bacteria. The antibacterial activity enhanced with the increase in chain length at acetal carbon atom in the order n-Pr>Et>Me.

Synthesis and antibacterial activity of novel phosphonium salts on the basis of pyridoxine.

A series of 13 phosphonium salts on the basis of pyridoxine derivatives were synthesized and their antibacterial activity against clinically relevant strains was tested in vitro. All compounds were almost inactive against gram-negative bacteria and exhibited structure-dependent activity against gram-positive bacteria. A crucial role of ketal protection group in phosphonium salts for their antibacterial properties was demonstrated.

Filled Pentagons and Electron Counting Rule for Boron Fullerenes.

We have revisited the general constructing schemes for a large family of stable hollow boron fullerenes with 80 + 8n (n = 0, 2, 3, ...

[Synthesis and modification of triterpenoids with two lupan backbones].

The first derivatives containing two lupan backbones were synthesized by the interaction of betulonic acid chloride with diols (ethylene glycol and diethylene glycol) and monoethanolamine. A modification of ring A of ethylene-l,2-bis(betulonnate) led to its bis(3beta-aminopropyloxy) and bis(3,4-seco-2-cyano) derivatives.

Spatial carrier confinement in core-shell and multishell nanowire heterostructures.

We have derived an analytical effective-mass model and employed first-principles density functional theory to study the spatial confinement of carriers in core-shell and multishell structured semiconductor nanowires. The band offset effect is analyzed based on the subband charge density distributions, which is strongly dependent upon the strain relaxation. First-principles calculation results for spatially confined Si/Ge and GaN/GaP nanowires indicate accumulation of a Ge-core hole gas and a GaN-core electron gas, respectively, in agreement with experimental observations.

Design rules for phase-matched terahertz surface electromagnetic wave generation by optical rectification in a nonlinear planar waveguide.

The theory of guided waves in metal-dielectric planar multilayer structures is applied to reduce the loss and maximize optical nonlinearity for efficient terahertz-field generation in a surface electromagnetic wave by femtosecond laser pulses confined in a (chi)((2)) nonlinear planar waveguide. For typical parameters of thin-film polymer waveguides and metal-dielectric interfaces, the optimal size of the (chi)((2)) waveguide core providing the maximum efficiency of terahertz plasmon-field generation is shown to be less than the wavelength of the optical pump field.

Transition from moderate to strong hydrogen bonds: its identification and physical bases in the case of O-H...O intramolecular hydrogen bonds.

A systematic investigation aimed at identifying the transition from moderate (M) to strong (S) hydrogen bonds (HBs) and the physical bases of the main geometry-based HB strength classifications reported in the literature has been undertaken using the quantum theory of atoms in molecules (QTAIM). Correlations between the Laplacian of the electron density (rho) at the O..

Guiding radar signals by arrays of laser-induced filaments: finite-difference analysis.

Circular arrays of plasma filaments induced by femtosecond laser pulses in atmospheric air are shown to support guided modes of electromagnetic radiation in the centimeter and millimeter wavelength range. With the refractive index of laser-induced filaments being lower than the refractive index of nonionized air, arrays of such filaments can serve as a structured waveguide cladding, providing an index guiding of radar signals in a nonionized gas region. In spite of attenuation of radar radiation induced by plasma absorption, filament-array waveguides are shown to enhance radar signal transmission relative to freely propagating radar beams.

Use of transcranial magnetic stimulation with measurement of motor evoked potentials in the acute period of hemispheric ischemic stroke.

Functional derangements in the brain during the acute period of ischemic hemispheric stroke (IS) were assessed in terms of the severity of the motor neurological deficit in the acute period of IS and neurophysiological measures of motor evoked potentials (MEP) using transcranial magnetic stimulation (TCMS). A total of 52 patients (23 women, 29 men, mean age 58.5 +/- 8.

[Surgical treatment of resistant ascites in patients with portal hypertension].

Surgical methods of treatment of diureticoresistant ascites in 198 patients with portal hypertension are analyzed: portocaval bypass (n = 16), lymphovenous anastomosis (n = 64), ductolysis (n = 24), and peritoneovenous bypass (n = 94). The most stable positive results was achieved after portocaval bypass, but it can be performed only in a small part of patients. Peritoneovenous bypass and lymphovenous anastomosis demonstrated shorter effect but they had less risk and were better tolerated than portocaval bypass.

[Use of "regeneration stimulator" in surgical treatment of postoperative ventral hernia].

During experimental hernioplasty with the application of the "Regeneration stimulator" in 38 dogs it was discovered that the rehabilitation period of the abdominal walls after the operation was considerably shorter. An experience with surgical treatment of 42 patients with postoperative ventral hernias is described. To remove the defect of the anterior abdominal wall by different intraoperative methods "the regeneration stimulator" was used in the zone of plasty.