Colloidal Assembly of Au-Quantum Dot-Au Sandwiched Nanostructures with Strong Plasmon-Exciton Coupling.

Strong plasmon-exciton coupling could occur in hybrid metal-dye/semiconductor nanostructures, where the fast energy exchange between plasmons and excitons leads to two new eigenmodes of the system, known as Rabi splitting. In experiments, strongly coupled nanosystems are difficult to obtain because they require some strict conditions, such as low plasmonic damping, small plasmon mode volume, and good spectral overlap. This work demonstrates strongly coupled metal-semiconductor nanostructures can be constructed using colloidal assembly.

Quantification of the Photon Absorption, Scattering, and On-Resonance Emission Properties of CdSe/CdS Core/Shell Quantum Dots: Effect of Shell Geometry and Volumes.

Reliable quantification of the optical properties of fluorescent quantum dots (QDs) is critical for their photochemical, -physical, and -biological applications. Presented herein is the experimental quantification of photon scattering, absorption, and on-resonance-fluorescence (ORF) activities of CdSe/CdS core/shell fluorescent QDs as a function of the shell sizes and geometries. Four spherical QDs (SQDs) with different diameters and four rod-like QDs (RQDs) with different aspect ratios (ARs) have been analyzed using UV-vis, fluorescence, and the recent polarized resonance synchronous spectroscopic (PRS2) methods.

Linear Extrapolation of the Analyte-Specific Light Scattering and Fluorescence Depolarization in Turbid Samples.

Anisotropy and depolarization are two interconvertible parameters in fluorescence and light scattering spectroscopy that describe the polarization distribution of emitted and scattered photons generated with linearly polarized excitation light. Whereas anisotropy is more frequently used in fluorescence literature for studying association/dissociation of fluorophore-bearing reagents, depolarization is more popular in the light-scattering literature for investigating the effect of scatterers' geometries and chemical compositions. Presented herein is a combined computational and experimental study of the scattering and fluorescence depolarization enhancement induced by light scattering in turbid samples.

Degradation kinetics of hexachlorobenzene over zero-valent magnesium/graphite in protic solvent system and modeling of degradation pathways using density functional theory.

Hexachlorobenzene (HCB), like many chlorinated organic compounds, has accumulated in the environment from agricultural and industrial activity. Because of its health risks and adverse impact on various ecosystems, remediation of this contaminant is of vital concern. The objective of this study is to evaluate the proficiency of activated magnesium metal in a protic solvent system to accomplish reductive dechlorination of HCB.

Mechanistic and computational studies of PCB 151 dechlorination by zero valent magnesium for field remediation optimization.

Polychlorinated biphenyls (PCBs) are banned in the U.S. but are persistent in the environment; current regulations provide an urgent need to remediate PCBs in a cost-effective way.