Electron Transfer and Associative Detachment in Low-Temperature Collisions of D(-) with H.

The interaction of D(-) with H was studied experimentally and theoretically at low temperatures. The rate coefficients of associative detachment and electron transfer reactions were measured in the temperature range 10-160 K using a combination of a cryogenic 22-pole trap with a cold effusive beam of atomic hydrogen. Results from quantum-mechanical calculations are in good agreement with the experimental data.

H/D exchange in reactions of OH(-) with D2 and of OD(-) with H2 at low temperatures.

Using a cryogenic linear 22-pole rf ion trap, rate coefficients for H/D exchange reactions of OH(-) with D2 (1) and OD(-) with H2 (2) have been measured at temperatures between 11 K and 300 K with normal hydrogen. Below 60 K, we obtained k1 = 5.5 × 10(-10) cm(3) s(-1) for the exoergic .

State specific stabilization of H+ + H2(j) collision complexes.

Stabilization of H3(+) collision complexes has been studied at nominal temperatures between 11 and 33 K using a 22-pole radio frequency (rf) ion trap. Apparent binary rate coefficients, k(*) = kr + k3[H2], have been measured for para- and normal-hydrogen at number densities between some 10(11) and 10(14) cm(-3). The state specific rate coefficients extracted for radiative stabilization, kr(T;j), are all below 2 × 10(-16) cm(3) s(-1).

Stabilization of H+-H2 collision complexes between 11 and 28 K.

Formation of H(3)(+) via association of H(+) with H(2) has been studied at low temperatures using a 22-pole radiofrequency trap. Operating at hydrogen number densities from 10(11) to 10(14) cm(-3), the contributions of radiative, k(r), and ternary, k(3), association have been extracted from the measured apparent binary rate coefficients, k*=k(r)+k(3)[H(2)]. Surprisingly, k(3) is constant between 11 and 22 K, (2.

Single-mode in-gap emission of medium-width photonic crystal waveguides on InP substrate.

In this paper, we present a numerical and experimental study of W3-4 photonic crystal (PhC) waveguide lasers fabricated on InP substrate. In such a PhC waveguide, the dispersion curve of the fundamental mode folds in the two-dimensional gap of the triangular lattice. Folding occurs at the Brillouin zone edge as in the case of genuine distributed feedback (DFB) lasers.

Near-field optical probing of two-dimensional photonic crystals: theory and experiment.

We report new experimental results, and their theoretical analysis, on the mechanisms that control light transfer between two integrated waveguides connected by two-dimensional matrices of dielectric pillars. The optical properties of the system are analysed from the well-established formalism of classical field susceptibilities (Green dyadic functions). We apply this scheme to investigate the optical properties of two-dimensional arrays connected to two integrated waveguides.