Hierarchical (Ni,Co)Se sheets for efficient oxygen evolution reaction electrocatalysis: a combined approach of fabrication control and mechanistic understanding.

We present a fabrication process for hierarchical (Ni,Co)Se sheets, achieving efficient oxygen evolution reaction (OER) activity with a 10 mA cm current density at an overpotential of 290 mV. Porous architecture and doping improve kinetics, supported by DFT calculations. This approach offers insights into designing stable, high-performance OER catalysts.

Ultrathin MoS Nanowire Network for High-Sensitivity Breathable Piezoresistive Electronic Skins.

Flexible piezosensing electronic skins (e-skins) have attracted considerable interest owing to their applications in real-time human-health monitoring, human-machine interactions, and soft bionic robot perception. However, the fabrication of piezosensing e-skins with high sensitivity, biological affinity, and good permeability at the same time is challenging. Herein, we designed and synthesized MoS nanowires by inserting [MoS] chains between MoS interlayers.

Modulating Cation Migration and Deposition with Xylitol Additive and Oriented Reconstruction of Hydrogen Bonds for Stable Zinc Anodes.

Highly reversible plating/stripping in aqueous electrolytes is one of the critical processes determining the performance of Zn-ion batteries, but it is severely impeded by the parasitic side reaction and dendrite growth. Herein, a novel electrolyte engineering strategy is first proposed based on the usage of 100 mM xylitol additive, which inhibits hydrogen evolution reaction and accelerates cations migration by expelling active H O molecules and weakening electrostatic interaction through oriented reconstruction of hydrogen bonds. Concomitantly, xylitol molecules are preferentially adsorbed by Zn surface, which provides a shielding buffer layer to retard the sedimentation and suppress the planar diffusion of Zn ions.

Tuning pyridinic-N and graphitic-N doping with 4,4'-bipyridine in honeycomb-like porous carbon and distinct electrochemical roles in aqueous and ionic liquid gel electrolytes for symmetric supercapacitors.

Doping engineering in nanostructured carbon materials is an effective approach to modify heteroatom species and surface electronic structures. Herein, an advanced electrode material based on a honeycomb-like porous carbon matrix with tunable N-doped configurations is prepared via 4,4'-bipyridine (4,4'-bpy)-assisted pyrolysis of SiO@ZIF-8 templates and subsequent etching treatment. Interestingly, the amounts of pyridinic-N and graphitic-N can be controlled by rationally varying the content of 4,4'-bpy which acts as the N source in the pyrolysis process.

Renewable P-type zeolite for superior absorption of heavy metals: Isotherms, kinetics, and mechanism.

Zeolite is a characteristic material for removing heavy metals exhibiting by low tolerance quantities. It is particularly desirable although challenging to cultivate an unmodified and reusable zeolite for eradicating heavy metals with great capacity. Herein, we sought out and firstly synthesized the uniform octahedral zeolite NaAlSiO·12HO for heavy metal ions trap, proven extraordinarily effective decontamination of M (Pb, Cd, Cu, and Zn).

ZnO-Templated Selenized and Phosphorized Cobalt-Nickel Oxide Microcubes as Rapid Alkaline Water Oxidation Electrocatalysts.

Oxygen electrocatalysis is of remarkable significance for electrochemical energy storage and conversion technologies, together with fuel cells, metal-air batteries, and water splitting devices. Substituting noble metal-based electrocatalysts by decidedly effective and low-cost metal-based oxygen electrocatalysts is imperative for the commercial application of these technologies. Herein, a novel strategy is presented to fabricate selenized and phosphorized porous cobalt-nickel oxide microcubes by using a sacrificial ZnO spherical template and the resulting microcubes are employed as an oxygen evolution reaction (OER) electrocatalyst.

Charge-Transfer-Promoted High Oxygen Evolution Activity of Co@CoS Core-Shell Nanochains.

Co@CoS nanochains with core-shell structures are prepared by a direct-current arc-discharge technique and followed sulfurization at 200 °C. The nanochains, which consist of uniform nanospheres connecting each other, can range up to several micrometers. The thickness of CoS shell can be changed by regulating the sulfurization time.

Oxygen Evolution Activity of Co-Ni Nanochain Alloys: Promotion by Electron Injection.

Metal alloy nanoparticles have shown promising applications in electrocatalysis. However, the nanoparticles usually suffer from limited charge-transfer efficiency, which can be solved by preparing one-dimensional materials. Herein, Co-Ni alloy nanochains are prepared by a direct-current arc-discharge method.

Crimean-Congo hemorrhagic fever: Risk factors and control measures for the infection abatement.

Crimean-Congo hemorrhagic fever (CCHF) is a vector-borne viral disease, widely distributed in different regions of the world. The fever is caused by the CCHF virus (CCHFV), which belongs to the genus and family. The virus is clustered in seven genotypes, which are Africa-1, Africa-2, Africa-3, Europe-1, Europe-2, Asia-1 and Asia-2.