Enhancing the selectivity for light olefins through catalytic cracking of n-hexane by phosphorus doping on lanthanum-modified ZSM-5.

Naphtha, as the primary raw material in the production of light olefins, could well accommodate their increasing demand through the energy-efficient process of catalytic cracking with ZSM-5. In the current work, different amounts of lanthanum and phosphorous were loaded on ZSM-5 using the wet impregnation method to tune the acidic properties of ZSM-5 for selective catalytic cracking of n-hexane to produce light olefins. Various characterization techniques such as X-ray diffraction (XRD), Al nuclear magnetic resonance (NMR), temperature-programmed desorption of NH (NH-TPD), Py-Fourier transform infra-red (Py-FTIR), inductively coupled plasma optical emission spectroscopy (ICP-OES), N adsorption-desorption, X-ray photoelectron spectra (XPS), and scanning electron microscopy were adopted to investigate the modified zeolites.

Study on the Formation Mechanism of Cold-Rolled Sludge and the Biodiesel Production from Sludge.

Cold-rolled sludge (CRS) has become a challenge due to its large volumetric capacity and high toxicity and is difficult to be degraded under natural conditions. This article aims to explore the feasibility of the solvent extraction method for recovering oil and fat from CRS and utilizing it as a raw material to prepare biodiesel with the application of a homogeneous catalyst HSO to mediate esterification and transesterification. The formation mechanism of CRS was proposed with its detailed analysis; hydroxylates were preferentially adsorbed on the metal surface by hydrogen bonds, and free fatty acids were hooked by carbon chains to form a second layer of adsorption.