Stapler Strategies for Upcycling Mixed Plastics.

Mechanical recycling is one of the simplest and most economical strategies to address ever-increasing plastic pollution, but it cannot be applied to immiscible mixed plastics and suffers from property deterioration after each cycle. By combining the amphiphilic block copolymer strategy and reactive compatibilization strategy, we designed a series of stapler strategies for compatibilizing/upcycling mixed plastics. First, various functionalized graft copolymers were accessed via different synthetic routes.

Dielectric Spectroscopy Monitoring of Silica Nanoparticle Synthesis in Cationic Water-in-Oil Microemulsions.

monitoring of microemulsion-based nanoparticle synthesis is significant for understanding the particle formation mechanism and for advancing controlled nanoparticle synthesis by this means. In this study, the processes of silica nanoparticle synthesis in a CTAB/-hexanol/cyclohexane/ammonia microemulsion were monitored via dielectric spectroscopy and in real time, with the influences of the water content and precursor concentration being considered. Two dielectric relaxations in addition to a water-induced one were observed in the frequency range of 1 MHz to 3 GHz, which persist throughout the synthesis processes.