Simulation studies on hydrogen sorption and its thermodynamics in covalently linked carbon nanotube scaffold.

Carbon nanotubes are potential hydrogen storage materials because of their large surface area and high sorbate-surface interaction energy due to the curvature effect. However, single walled carbon nanotubes bundle up tightly, so most of their surface areas become inaccessible for adsorption. As a solution, spacer molecules can be used to hold the tubes at a distance from each other in a scaffolded structure.

Enzymatic treatment of sulfonated aromatic amines generated from reductive degradation of reactive azo dyes.

Anaerobic degradation, an effective treatment process of textile industry effluent, generates sulfonated aromatic amines, which are carcinogenic, mutagenic, and resistant to microbial degradation. These aromatic amines can be effectively removed by oxidative polymerization catalyzed by peroxidase enzyme. The amines, generated in this study from the anaerobic reduction by zero-valent iron of two reactive azo dyes (Reactive Red 2 [RR2] and Reactive Black 5 [RB5]), were successfully removed (90%) by Arthromyces ramosus peroxidase (ARP).