pH-Dependent Polyelectrolyte Bridging of Charged Nanoparticles.

Systems comprised of polyelectrolytes and charged nanoparticles are of great technological interest, being common components in formulations among other uses. The colloidal stability of formulations is an important issue, and thus a lot of effort has been made to study the interactions of individual components in these systems. Here, the complexation and adsorption of an annealed (pH-dependent) polyelectrolyte to two spherical nanoparticles has been studied using coarse-grained Monte Carlo simulations.