Efficient Europium Sensitization via Low-Level Doping in a 2-D Bismuth-Organic Coordination Polymer.

A new bismuth-organic compound containing 1,10-phenanthroline (phen) and 2,5-pyridinedicarboxylic acid (PDC) was synthesized and structurally characterized by single-crystal X-ray diffraction. The structure consists of 2-D {Bi(phen)(HPDC)(PDC)} sheets wherein the PDC ligands bridge metal centers via three unique bonding modes. The 2-D sheets are further connected through strong hydrogen-bonding interactions to form a 3-D supramolecular network.

Synthesis and Characterization of Cerium-Oxo Clusters Capped by Acetylacetonate.

Cerium-oxo clusters have applications in fields ranging from catalysis to electronics and also hold the potential to inform on aspects of actinide chemistry. Toward this end, a cerium-acetylacetonate (acac) monomeric molecule, Ce(acac) (), and two acac-decorated cerium-oxo clusters, [CeO(acac)(CHO)(CHOH)]·10.5MeOH () and [CeO(OH)(acac)(CHCOO)]·6(CHCN) (), were prepared and structurally characterized.