Synthesis, kinetics, mechanisms, and bioactivity evaluations of a novel Zn(ii) complex.

Zn(ii)-based anticancer drugs can be suitable alternatives to conventional Pt(ii)-based drugs because of the unique chemical properties of Zn(ii) and low toxicity. In this study, a new hexadentate and heteroleptic Zn(ii) complex ([Zn(bpy)(OAc)], 1) was prepared with a conventional ,-donor ligand (2,2'-bipyridine) and a leaving group (OAc) and characterized ESI-MS, UV-Vis, and FT-IR spectroscopy. Kinetic and mechanistic investigations of 1 were performed using two biologically relevant ligands (dl-penicillamine and l-cysteine) to understand its selectivity and reactivity.

Optimizing methylene blue adsorption conditions on hydrothermally synthesized NaX zeolite through a full two-level factorial design.

Besides being hazardous to humans and aquatic organisms, dyes present in water reservoirs limit sunlight's availability to aquatic plants and animals, making significant impact on their growth and development. Herein, the adsorptive removal of methylene blue (MB) dye from aqueous solution using type X (NaX) zeolite by full experimental design 2 was studied. The physical and chemical properties of NaX zeolite were identified using various characterization techniques such as X-ray diffraction (XRD), scanning electron microscopy with energy dispersive X-ray (SEM-EDS), Fourier transform infra-red (FT-IR), and Brunauer-Emmett-Teller (BET) surface area analyses.

Nanocellulose reinforced polyvinyl alcohol-based bio-nanocomposite films: improved mechanical, UV-light barrier, and thermal properties.

This study reported the development and characterisation of bio-nanocomposite films based on the polyvinyl alcohol (PVA) reinforced with cellulose nanofibres (CNFs) of different concentrations (1-5 wt%), isolated from pineapple leaf fibre high-shear homogenisation and ultrasonication. The PVA film and bio-nanocomposite were prepared using a solution casting method. The PVA film and bio-nanocomposite samples were characterized using FE-SEM, XRD, FTIR spectroscopy, UV-vis spectroscopy in transmission mode, TGA, and DTG.

Surviving chlorinated waters: bleaching sensitivity and persistence of free-living amoebae.

Recent advancements in membrane technologies and disinfection methods have enhanced drinking water quality significantly. However, microorganisms, including free-living amoebae (FLA), persist and pose potential threats to humans. FLA are linked to severe neuro-ophthalmic infections and serve as hosts of pathogenic bacteria.

Microalgal and activated sludge processing for biodegradation of textile dyes.

The textile industry contributes substantially to water pollution. To investigate bioremediation of dye-containing wastewater, the decolorization and biotransformation of three textile azo dyes, Red HE8B, Reactive Green 27, and Acid Blue 29, were considered using an integrated remediation approach involving the microalga Chlamydomonas mexicana and activated sludge (ACS). At a 5 mg L dye concentration, using C.

Two-Phase Crude Oil-Water Flow Through Different Pipes: An Experimental Investigation Coupled with Computational Fluid Dynamics Approach.

The present study deals with two-phase non-Newtonian pseudoplastic crude oil and water flow inside horizontal pipes simulated by ANSYS. The study helps predict velocity and velocity profiles, as well as pressure drop during two-phase crude-oil-water flow, without complex calculations. Computational fluid dynamics (CFD) analysis will be very important in reducing the experimental cost and the effort of data acquisition.

Enhanced mono-aromatics production by the CH-assisted pyrolysis of microalgae using Zn-based HZSM-5 catalysts.

This study presents the catalytic pyrolysis of microalgae, Chlorella vulgaris (C. vulgaris), using pure CH and H-rich gas evolved from CH decomposition on three different HZSM-5 catalysts loaded with Zn, Ga, and Pt, aimed specifically at producing high-value mono-aromatics such as benzene, toluene, ethylbenzene, and xylene (BTEX). In comparison with that for the typical inert N environment, a pure CH environment increased the bio-oil yield from 32.

Fractional condensation of bio-oil vapors from pyrolysis of various sawdust wastes in a bench-scale bubbling fluidized bed reactor.

The use of lignocellulosic waste as an energy source for substituting fossil fuels has attracted lots of attention, and pyrolysis has been established as an effective technology for this purpose. However, the utilization of bio-oil derived from non-catalytic pyrolysis faces certain constraints, making it impractical for direct application in advanced sectors. This study has focused on overcoming these challenges by employing fractional condensation of pyrolytic vapors at distinct temperatures.

Catalytic pyrolysis of harmful plastic waste to alleviate environmental impacts.

Wax is a detrimental byproduct of plastic waste pyrolysis causing challenges upon its release into the environment owing to persistence and potential toxicity. In this study, the valorization of wax materials through conversion into BTEX (i.e.

Synthesis, Kinetics, Reaction Mechanism, and Bioactivity Assays of a Dimeric Palladium Complex.

A dimer of Pd(II), [(bpy)Pd(μ-OH)Pd(bpy)], (complex ) (where bpy = 2,2'-bipyridyl) has been synthesized at physiological pH (7.4) and characterized by electronic spectroscopy, electrospray ionization mass spectrometry (ESI-MS) spectroscopy, and Fourier transform infrared (FT-IR) analysis. Reaction kinetics of with glycine (LH), l-glutamic acid (LH), and l-arginine (LH) were investigated in an aqueous medium at pH of 7.

Enhanced Mitochondrial Targeting and Inhibition of Pyroptosis with Multifunctional Metallopolyphenol Nanoparticles in Intervertebral Disc Degeneration.

Intervertebral disc degeneration (IVDD) is a significant contributor to low back pain, characterized by excessive reactive oxygen species generation and inflammation-induced pyroptosis. Unfortunately, there are currently no specific molecules or materials available to effectively delay IVDD. This study develops a multifunctional full name of PG@Cu nanoparticle network (PG@Cu).

Photoelectrocatalytic treatment of municipal wastewater with emerging concern pollutants using modified multi-layer catalytic anode.

Municipal wastewater contains emergent chemical and biological pollutants that are resistant to conventional wastewater treatments. Therefore, the focus of the current study was to address the challenge of removing emergent chemical and biological pollutants present in municipal wastewater. To achieve this, a photo electro-catalytic (PEC) treatment approach was employed, focusing on the removal of both micro and biological pollutants that are of emergent concern, as well as the reduction of Chemical Oxidation Demand (COD) and Total Organic Carbon (TOC).

Electroconductive bioplatform based on dextrin for the immobilization of hemoglobin: Application for electrochemical monitoring of HO.

A novel biodegradable dextrin-based nanocomposite, involving polypyrrole (PPy) and hydrophilic dextrin (Dex) (PPy@Dex) was prepared using in-situ radical chemical polymerization technique. The obtained PPy@Dex bionanocomposite was fully characterized by FT-IR, XRD, FESEM, and DSC methods. The exceptional properties such as biocompatibility, high surface area, the proper functional group on the surface, and outstanding electrical conductivity of synthesized bionanocomposite made it a superior candidate over biomolecules immobilization.

Co-Carbonized Waste Polythene/Sugarcane Bagasse Nanocomposite for Aqueous Environmental Remediation Applications.

The conversion of worthless municipal solid wastes to valuables is a major step towards environmental conservation and sustainability. This work successfully proposed a technique to utilize the two most commonly available municipal solid wastes viz polythene (PE) and sugarcane bagasse (SB) for water decolorization application. An SBPE composite material was developed and co-pyrolyzed under an inert atmosphere to develop the activated SBPEAC composite.

A Novel Chitosan/Nano-Hydroxyapatite Composite for the Adsorptive Removal of Cd(II) from Aqueous Solution.

A novel polymer bio-composite based on nano-hydroxyapatite (n-Hap) and chitosan (CS) (CS/n-Hap) was synthesized to effectively address toxic cadmium ions removal from water. The composition and structure of CS/n-Hap bio-composite were analyzed through different characterization techniques. XRD patterns affirmed that the crystalline structure of n-Hap remained unaltered during CS/n-Hap synthesis, while FT-IR spectrum sustained all the characteristic peaks of both CS and n-Hap, affirming the successful synthesis of CS/n-Hap.

Dissemination of sulfonamide resistance genes in digester microbiome during anaerobic digestion of food waste leachate.

The preeminence of sulfonamide drug resistance genes in food waste (FW) and the increased utilization of high-strength organic FW in anaerobic digestion (AD) to enhance methane production have raised severe public health concerns in wastewater treatment plants worldwide. In this regard, the dissemination patterns of different sulfonamide resistance genes (sul1 and sul2) and their impact on the digester core microbiota during AD of FW leachate (FWL) were evaluated. The presence of various sulfonamide antibiotics (SAs) in FWL digesters improved the final methane yield by 37 % during AD compared with FWL digesters without SAs.

Chitin-Based Magnesium Oxide Biocomposite for the Removal of Methyl Orange from Water.

In this work, a cost-effective chitin-based magnesium oxide (CHt@MgO) biocomposite with excellent anionic methyl orange (MO) dye removal efficiency from water was developed. The CHt@MgO biocomposite was characterized by FT-IR, XRD, SEM-EDX, and TGA/DTG. Results proved the successful synthesis of CHt@MgO biocomposite.

Hydrothermal Conversion of Food Waste to Carbonaceous Solid Fuel-A Review of Recent Developments.

This review critically discussed recent developments in hydrothermal carbonization (HTC) of food waste and its valorization to solid fuel. Food waste properties and fundamentals of the HTC reactor were also covered. The review further discussed the effect of temperature, contact time, pressure, water-biomass ratio, and heating rate on the HTC of food waste on the physiochemical properties of hydrochar.