Polymers (Basel)
June 2024
With the increasing water consumption, water evaporators have been investigated for clean water production. Herein, the fabrication of electrospun composite membrane evaporators based on ethyl cellulose (EC), with the incorporation of light-absorption enhancers 2D MoS and helical carbon nanotubes, for steam generation and solar desalination is described. Under natural sunlight, the maximum water evaporation rate was 2.
View Article and Find Full Text PDFInt J Biol Macromol
July 2023
In this work, a novel poly (methylenelactide--L-lactide), P(MLA--LLA) graft copolymer was synthesized from poly(methylenelactide) (PMLA) and L-lactide (LLA) using 0.03 mol% liquid tin(II) -butoxide (Sn(OBu)) as an initiator by a combination of vinyl addition and ring-opening polymerization (ROP) at 120 °C for 72 h. Proton and carbon-13 nuclear magnetic resonance spectroscopy (H- and C-NMR) and Fourier-transform infrared spectroscopy (FT-IR) confirmed the grafted structure of P(MLA--LLA).
View Article and Find Full Text PDFNovel soluble liquid tin(ii) -butoxide (Sn(OCH)), tin(ii) -hexoxide (Sn(OCH)), and tin(ii) -octoxide (Sn(OCH)) initiators were synthesized for use as coordination-insertion initiators in the bulk ring-opening polymerization (ROP) of l-lactide (LLA). In order to compare their efficiencies with the more commonly used tin(ii) 2-ethylhexanoate (stannous octoate, Sn(Oct)) and conventional tin(ii) octoate/-alcohol (SnOct/ROH) initiating systems, kinetic parameters derived from monomer conversion data were obtained from non-isothermal differential scanning calorimetry (DSC). In this work, the three non-isothermal DSC kinetic approaches including dynamic (Kissinger, Flynn-Wall, and Ozawa); isoconversional (Friedman, Kissinger-Akahira-Sunose (KAS) and Ozawa-Flynn-Wall (OFW)); and Borchardt and Daniels (B/D) methods of data analysis were compared.
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