Thermally enhanced solid-liquid separation process in food waste biorefinery: modelling the anaerobic digestion of solid residues.

The biochemical valorization potential of food waste (FW) could be exploited by extracting decreasing added-value bio-based products and converting the final residues into energy. In this context, multi-purpose and versatile schemes integrating thermal and biochemical conversion processes will play a key role. An upstream thermal pretreatment + solid-liquid separation unit was here proposed to optimize the conversion of the liquid fraction of FW into valuable chemicals through semi-continuous fermentation process, and the conversion of the residual solid fraction into biomethane through anaerobic digestion.

Medium chain Fatty acids production from Food Waste via homolactic fermentation and lactate/ethanol elongation: Electron balance and thermodynamic assessment.

This study explored the potential of Food Waste (FW) extract as a suitable substrate for Medium Chain Fatty Acids (MCFAs) production, in a single-phase reactor, where both fermentation and Chain Elongation (CE) processes occurred simultaneously. A continuous experiment was conducted with an Organic Loading Rate (OLR) = 20 gCOD L d and was fed in batch mode twice a week with pH = 6. In addition, four batch tests were performed, to assess the effects on the MCFAs production of caproate inhibition, hydrogen partial pressure (P) and different lactate/acetate ratios.

Mathematical modelling of an intermittent anoxic/aerobic MBBR: Estimation of nitrification rates and energy savings.

This study aimed at modelling the performance of a novel MBBR configuration, named A/O-MBBR, comprised of a pre-anoxic reactor, with an HRT of 4.5 h, coupled with an intermittent anoxic/aerobic MBBR (HRT = 6.8 h).

Direct Conversion of Food Waste Extract into Caproate: Metagenomics Assessment of Chain Elongation Process.

In a circular economy strategy, waste resources can be used for the biological production of high added-value substances, such as medium chain fatty acids (MCFAs), thus minimising waste and favouring a sustainable process. This study investigates single-stage fermentation processes for the production of MCFAs in a semi-continuous reactor treating the extract of real food waste (FW), without the addition of external electron donors. Two sequential acidogenic fermentation tests were carried out at an organic loading rate (OLR) of 5 and 15 gCOD Ld with a hydraulic retention time of 4 days and pH controlled at 6 ± 0.

Kitchen waste valorization through a mild-temperature pretreatment to enhance biogas production and fermentability: Kinetics study in mesophilic and thermophilic regimen.

Biowaste valorization through anaerobic digestion is an attractive option to achieve both climate protection goals and renewable energy production. In this paper, a complete set of batch trials was carried out on kitchen waste to investigate the effects of mild thermal pretreatment, temperature regimen and substrate/inoculum ratio. Thermal pretreatment was effective in the solubilisation of macromolecular fractions, particularly carbohydrates.

Anaerobic digestion of mixed urban biowaste: The microbial community shift towards stability.

Anaerobic digestion is applied worldwide to treat food waste (FW) with the aim of obtaining renewable bioenergy by exploiting the methane gas produced. However, there are several problems in practical applications, primarily due to system instability. Although exhaustive knowledge regarding anaerobic microbial community composition has been established, few studies have investigated long-term correlations between microbial consortia, operative conditions and feedstock characteristics.

Anaerobic co-digestion of food waste and waste activated sludge: ADM1 modelling and microbial analysis to gain insights into the two substrates' synergistic effects.

The reasons for the acidification problem affecting Food Waste (FW) anaerobic digestion were explored, combining the outcomes of microbiological data (FISH and CARD-FISH) and process modelling, based on the Anaerobic Digestion Model n°1 (ADM1). Long term semi continuous experiments were carried out, both with sole FW and with Waste Activated Sludge (WAS) as a co-substrate, at varying operational conditions (0.8-2.

Variability of food waste chemical composition: Impact of thermal pre-treatment on lignocellulosic matrix and anaerobic biodegradability.

A comprehensive sustainable Food Waste (FW) management is globally needed in order to reduce the environmental pollution and the financial costs due to FW disposal; anaerobic digestion is considered as one of the best environmental-friendly alternatives to this aim. A deep investigation of the chemical composition of different Food waste types (cooked kitchen waste (CKW), fruit and vegetable scraps (FVS) and organic fraction of municipal solid waste (OFMSW)) is here reported, in order to evaluate their relevant substance-specific properties and their impact on anaerobic biodegradability by means of a sophisticated automatic batch test system. Suitability for a mild thermal pre-treatment (T = 134 °C and p = 3.

Biomethane potential of food waste: modeling the effects of mild thermal pretreatment and digestion temperature.

In order to enhance anaerobic biodegradability of food waste (FW), thermal pretreatment was applied. The effectiveness in terms of biodegradability extent and process rate improvement was investigated. To this aim, Biomethane Potential tests were carried out under mesophilic and thermophilic conditions.

Physicochemical regeneration of high silica zeolite Y used to clean-up water polluted with sulfonamide antibiotics.

High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategies for the exhausted zeolite regeneration, the efficacy of some chemico-physical treatments on the zeolite loaded with four different sulfonamides was evaluated. The evolution of photolysis, Fenton-like reaction, thermal treatments, and solvent extractions and the occurrence in the zeolite pores of organic residues eventually entrapped was elucidated by a combined thermogravimetric (TGA-DTA), diffractometric (XRPD), and spectroscopic (FT-IR) approach.

Chemical characterization of municipal wastewater sludges produced by two-phase anaerobic digestion for biogas production.

In the present study, the chemical features of municipal wastewater sludges treated in two-phase separate digesters (one for acetogenesis and the other one for methanogenesis), were characterized by using chemical analysis, stable carbon isotope ratios (delta(13)C), HS-SPME-GC-MS, TG-DTA analysis and DRIFT spectroscopy. The results obtained showed that sludges from acetogenesis and methanogenesis differed from each other, as well as from influent raw sludges. Both processes exhibited a diverse chemical pattern in term of VFA and VOC.

TG-DTA, DRIFT and NMR characterisation of humic-like fractions from olive wastes and amended soil.

The purpose of the present study is to investigate, by means of thermogravimetric analysis (TG) and differential thermal analysis (DTA), diffuse reflectance infrared Fourier transform (DRIFT) and 2D nuclear magnetic resonance (NMR) spectroscopies, the structural features of the humic-like fraction (HLF) from olive pulp (OP), its effluents originated from the fermentation processes for hydrogen (EH2) and methane production (ECH4) and humic acid (HA) from soil amended with each of these materials. A considerable structural modification emerged between the HLF, in particular from the ECH4 effluent, which was characterised by a high content of polyphenolic and polypeptidic substances. The short-term amendment trial with OP and EH2 indicated that no chemical or structural changes in soil HA appeared.

Characterisation of Ca- and Al-pectate gels by thermal analysis and FT-IR spectroscopy.

Thermal analysis (TG-DTA) and FT-IR spectroscopy have been performed on calcium-pectate membranes to investigate their structure and the consequent variation caused by aluminium sorption. Calcium-polygalacturonate (Ca-PG) membranes, model systems of the soil-root interface, were exposed to aluminium solutions at different concentrations (25-800 microM). Three different pHs (3.

Quantitative estimation of peat, brown coal and lignite humic acids using chemical parameters, 1H-NMR and DTA analyses.

Humic acids extracted from peats (P), brown coals (BC) and lignites (L), were characterized using different (chemical, 1H-nuclear magnetic resonance spectroscopy and differential thermal analysis) techniques. Fourteen variables were obtained from these analyses and only five were selected because uncorrelated in multiple partial correlation. The chosen variables were C concentration, aliphatic and aromatic components and the heat of reaction of the second exothermic peak.