Unlabelled: In the present study, CeO nanoparticles were synthesized using one-pot green route with high yield using microalgae The synthesized CeO nanoparticles (CeO-np) exhibited rapid photocatalytic degradation 98.2% of doxycycline (DC) (20 mg/L) in only 30 min under visible light at pH7 in water. It was encouraging that CeO-np did not demonstrate a loss of photocatalytic activity up to five repeated cycles, confirming its stability during the degradation process.
View Article and Find Full Text PDFEmerging contaminants (ECs) in the environment are a cause of concern due to their potential toxic effects. The study investigates the fate of 20 ECs covering a wide range of physical-chemical properties in ten full-scale municipal wastewater treatment plants (WWTPs). The plants were based on conventional technologies such as waste stabilization pond, upflow sludge blanket reactor, activated sludge process, and biological nutrient removal-based technologies such as anoxic-aerobic process, anaerobic-anoxic-aerobic process, biodenipho process, sequencing batch reactor, and densadeg-biofor process.
View Article and Find Full Text PDFThe study aims to understand the occurrence and removal of 20 emerging contaminants (ECs) in each unit process of a sequencing batch reactor-based wastewater treatment plant (WWTP) and explore the potential of biological activated carbon (BAC) for the treatment of residual ECs and organic matter in the secondary effluent. Analgesic-acetaminophen, anti-inflammatory drug-ibuprofen, and stimulant-caffeine were detected at high concentrations in the influent. Most of the removal was observed in the biological treatment stage in the SBR basins.
View Article and Find Full Text PDFEmerging contaminants (ECs) are a growing concern for the environment and human health. The study investigates 20 commonly reported ECs in 10 wastewater treatment plants (WWTPs) in urban to semi-urban settlements of north India over two years in the summer and winter. The selected plants were based on waste stabilization pond (WSP), up-flow anaerobic sludge blanket (UASB), activated sludge process (ASP), anoxic-aerobic process (AO), anaerobic-anoxic-oxic process, biodenipho process, sequencing batch reactor, and densadeg-biofor process.
View Article and Find Full Text PDFBiodegradation of terephthalate (TPA) is a highly desired catabolic process for the bacterial utilization of this polyethylene terephthalate (PET) depolymerization product, but to date, the structure of terephthalate dioxygenase (TPDO), a Rieske oxygenase (RO) that catalyzes the dihydroxylation of TPA to a -diol, is unavailable. In this study, we characterized the steady-state kinetics and first crystal structure of TPDO from Comamonas testosteroni KF1 (TPDO). TPDO exhibited substrate specificity for TPA (/ = 57 ± 9 mM s).
View Article and Find Full Text PDFThe study investigates the fate of 20 contaminants of emerging concern (CECs) in two full-scale wastewater treatment plants (WWTPs) based on the Biodenipho™ (WWTP 1) and anaerobic-anoxic-oxic (WWTP 2) processes. Samples of both the dissolved and solid phases (particulate and sludge) from all the wastewater and sludge processing-related units were studied using the mass balance approach to understand the distribution of CECs. The total mass load removal efficiency for anti-inflammatory (4), antibiotics (4), and hormones (5) was 76, 46, 93%, and 72, 38, 90% from WWTP 1 and 2, respectively.
View Article and Find Full Text PDFManagement of agro-waste is a major challenge globally due to inefficient disposal techniques, which concominantly leads pollution and loss of renewable bioenergy. Anaerobic digestion of agro-waste is one of the ways to tackle this problem but hindered by the recalcitrant nature of agro-waste. This study investigated the effect of granular activated carbon (GAC) and granular biochar (GBC) addition to enhance the thermophilic anaerobic co-digestion of wheat husk and sewage sludge.
View Article and Find Full Text PDFPharmaceuticals, personal care products, synthetic hormones, and industrial manufacturing additives are used worldwide, and their residues are frequently detected in wastewater. In this study, a sensitive and selective method was developed and validated for the detection and quantification of 14 Emerging Contaminants (ECs) with various physico-chemical properties frequently found in wastewater. Solid Phase Extraction (SPE) allowed for extraction and concentration of the compounds.
View Article and Find Full Text PDF