Geochemical and Isotope Study of Trichloroethene Degradation in a Zero-Valent Iron Permeable Reactive Barrier: A Twenty-Two-Year Performance Evaluation.

This study provides a twenty-two-year record of in situ degradation of chlorinated organic compounds by a granular iron permeable reactive barrier (PRB). Groundwater concentrations of trichloroethene (TCE) entering the PRB were as high as 10670 μg/L. Treatment efficiency ranged from 81 to >99%, and TCE concentrations from <1 μg/L to 165 μg/L were detected within and hydraulically down-gradient of the PRB.