Simultaneously promoting the surface/bulk structural stability of Fe/Mn-based layered cathode for sodium ion batteries.

Layered sodium iron manganese oxide cathodes have attracted great interest owing to their high specific capacity and cost-effective metal resources, while the detrimental phase transitions and surface structural degradation severely limit their commercial applications. In this work, the bulk and surface structure stability of a P2-NaFeMnO cathode can be synergically enhanced by a one-step Li/Nb co-doping strategy. Structural characterizations reveal that Li doping promotes the formation of P2/O3 biphasic structure and makes the unfavorable P2-OP4 phase transition convert into a smooth solid-solution reaction.