Retraction of 'Aqueous aerobic oxidation of alkyl arenes and alcohols catalyzed by copper(II) phthalocyanine supported on three-dimensional nitrogen-doped graphene at room temperature' by Mojtaba Mahyari , , 2014, , 7855-7857, https://doi.org/10.1039/C4CC01406E.
View Article and Find Full Text PDFAchieving an efficient catalyst in the ATRP system with a simple design, preparation from available materials, and high recyclability is a significant challenging issue. To attain the goal, herein, we used chitosan (CS)-modified cellulose filter paper (FP) as a green support for the synthesis of dip catalyst. The preparation of this catalyst involved surface treatment of the FP strips by CS coating through a dipping method, which increased the affinity of the substrate for adsorbing copper ions in the next step.
View Article and Find Full Text PDFA novel ammonia (NH) chemical sensor is presented with ultra-high response, good selectivity, fast response, and long-term stability using detecting layer of polyaniline/cupric oxide nanoparticles supported on three-dimensional nitrogen-doped graphene-based frameworks (PANI/CuO@3D-NGF) nanocomposite. The NH gas sensing response of the PANI/CuO@3D-NGF nanocomposite was studied by resistivity method in low concentration range of 50 ppb-100 ppm at room temperature. The PANI/CuO@3D-NGF nanocomposite was prepared through in situ polymerization of PANI on the CuO@3D-NGF with a high surface area.
View Article and Find Full Text PDFIn this paper, we presented the fabrication and properties of new ammonia (NH) sensors with sensitive layer of nickel nanoparticles decorated on three-dimensional nitrogen-doped graphene-based frameworks/polyaniline (NiNPs@3D-(N)GFs/PANI) hybrid. The hybrid are synthesized through in-situ oxidative polymerization on flexible thin substrate. Synergetic behavior between both components manifested outstanding sensitivity (750.
View Article and Find Full Text PDFIntroducing a new class of chiral selectors is an interesting work and this issue is still one of the hot topics in separation science and chirality. In this study, for the first time, sulfated maltodextrin (MD) was synthesized as a new anionic chiral selector and then it was successfully applied for the enantioseparation of five basic drugs (amlodipine, hydroxyzine, fluoxetine, tolterodine, and tramadol) as model chiral compounds using CE. This chiral selector has two recognition sites: a helical structure and a sulfated group which contribute to three corresponding driving forces; inclusion complexation, electrostatic interaction, and hydrogen binding.
View Article and Find Full Text PDFWe are introducing graphene oxide modified with amine groups as a new solid phase for extraction of heavy metal ions including cadmium(II), copper(II), nickel(II), zinc(II), and lead(II). Effects of pH value, flow rates, type, concentration, and volume of the eluent, breakthrough volume, and the effect of potentially interfering ions were studied. Under optimized conditions, the extraction efficiency is >97 %, the limit of detections are 0.
View Article and Find Full Text PDFCopper(ii) tetrasulfophthalocyanine supported on three-dimensional nitrogen-doped graphene-based frameworks was synthesized and introduced as a bifunctional catalyst for selective aerobic oxidation of alkyl arenes and alcohols to the corresponding carbonyl compounds. The ease of catalyst separation, high turnover, low catalyst loading and recyclability could potentially render it applicable in industrial setting.
View Article and Find Full Text PDFThe ordered carbohydrate-derived porous carbons (OC-DPCs) were first functionalized with thiol groups (-SH) and then immobilized with gold nanoparticles (AuNPs). The Au-SH-OC-DPCs were characterized by CHN analysis, transmission electron microscopy (TEM), fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and x-ray diffraction (XRD). The Au-SH-OC-DPCs were applied for the fabrication of a new electrochemical sensor.
View Article and Find Full Text PDFComb Chem High Throughput Screen
December 2013
A Passerini-type condensation for the synthesis of α-acyloxycarboxamides starting from simple and readily available inputs, including an isocyanide, aldehydes and water in the presence of trimethylsilyl azide as a catalyst under reflux conditions in toluene in good yields, is described.
View Article and Find Full Text PDFGraphene oxide-cobalt phthalocyanine (GO-PcCo) hybrid material as a new electrocatalyst was synthesized and used successfully to fabrication of new biosensor for the electrooxidation of l-cysteine (CSH) in aqueous media. Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM) images revealed that cobalt phthalocyanine is covalently attachment on graphene oxide sheets as single layers GO-PcCo. Cyclic voltammetric studies showed that the GO-PcCo/glassy carbon electrode (GO-PcCo/GCE) improves electrochemical behavior of CSH oxidation, as compared to the GO and PcCo.
View Article and Find Full Text PDFIn this work, two novel isocyanide-based multicomponent reactions of 1,2-diamine compounds with diketene have been developed as efficient strategies for the synthesis of 2,3,4,5-tetrahydro-1H-benzo[b][1,4]diazepine-2-carboxamides with regiochemical control and 1,6-dihydropyrazine-2,3-dicarbonitriles in good to excellent yields at ambient temperature.
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