Industrial organic dyes represent a significant portion of pollutants discharged into the environment, particularly by the textile industry. These compounds pose serious threats to living organisms due to their high toxicity. Various techniques have been explored for the degradation of organic dyes, among which heterogeneous photocatalysis utilising titanium dioxide (TiO) stands out as a promising technology.
View Article and Find Full Text PDFMolecules
September 2023
In this research, activated carbon (AC) was synthesized from ligno-cellulosic residues of wood chips (AKTW) using two-step semi-carbonization and subsequent pyrolysis using microwave-induced heating (MWP) in the presence of a mild activating agent of KCO. The influence of process input variables of microwave power (), residence time (), and amount of KCO () were analysed to yield superior quality carbon having maximum removal efficiencies () for lead (II) cations from waste effluents, fixed carbon percentages (), and carbon yield percentages (). Analysis of variance (ANOVA) was used to develop relevant mathematical models, with an appropriate statistical assessment of errors.
View Article and Find Full Text PDFFunctionalized magnetite nanoparticles (FeO) were prepared using the coprecipitation method followed by functionalization with a multipotent antioxidant (MPAO). The MPAO was synthesized and analyzed using FTIR and NMR techniques. In this study, the functionalized nanoparticles (IONP@AO) were produced and evaluated using the FTIR, XRD, Raman, HRTEM, FESEM, VSM, and EDX techniques.
View Article and Find Full Text PDFFood Addit Contam Part A Chem Anal Control Expo Risk Assess
August 2021
Food fraud is a global problem raising increased concerns during the past decades and food authenticity is now a burning issue. Beef, buffalo, chicken, duck, goat, sheep, and pork are heavily consumed meats bearing nutritional, economic and cultural/religious importance and are often found to be adulterated in raw and processed states. To authenticate these species, we developed and validated a highly specific multiplex (heptaplex) PCR assay targeting short length amplicons (73-263 bp) using seven pairs of species-specific primer sets targeting mitochondrial cytochrome b (cytb) and NADH dehydrogenase subunit 5 (ND5) genes.
View Article and Find Full Text PDFIn this study, activated carbon (AC) from coconut shell, as a widely available agricultural waste, was synthesised in a simple one-step procedure and used to produce a magnetic FeO/AC/TiO nano-catalyst for the degradation of methylene blue (MB) dye under UV light. Scanning electron microscopy revealed that TiO nanoparticles, with an average particle size of 45 to 62 nm, covered the surface of the AC porous structure without a reunion of its structure, which according to the TGA results enhanced the stability of the photocatalyst at high temperatures. The photocatalytic activities of synthesised AC, commercial TiO, FeO/AC, and FeO/AC/TiO were compared, with FeO/AC/TiO (1:2) exhibiting the highest catalytic activity (98%).
View Article and Find Full Text PDFCellulose constitutes most of a plant's cell wall, and it is the most abundant renewable polymer source on our planet. Given the hierarchical structure of cellulose, nanocellulose has gained considerable attention as a nano-reinforcement for polymer matrices in various industries (medical and healthcare, oil and gas, packaging, paper and board, composites, printed and flexible electronics, textiles, filtration, rheology modifiers, 3D printing, aerogels and coating films). Herein, nanocellulose is considered as a sustainable nanomaterial due to its substantial strength, low density, excellent mechanical performance and biocompatibility.
View Article and Find Full Text PDFHerein, we report the facile synthesis of Iron oxide@Pt core-shell nanoparticles (NPs) by facile two step synthesis process. The first step follows the growth of iron oxide nanoparticle by thermal decomposition process while the second step deals with the formation of iron oxide@Pt core-shell nanoparticles by the chemical reduction method. The synthesized core-shell nanoparticles were characterized by several techniques and used for the catalytic reductive translation of Cr(VI) to Cr(III) in the presence of formic acid by a UV-vis spectrophotometer.
View Article and Find Full Text PDFIn this work, a simple, co-precipitation technique was used to prepare un-doped, pure tin oxide (SnO₂). As synthesized SnO₂ nanoparticles were doped with Cu ions. Detailed characterization was carried out to observe the crystalline phase, morphological features and chemical constituents with opto-electrical and magnetic properties of the synthesized nanoparticles (NPs).
View Article and Find Full Text PDFNowadays, owing to their large surface area, enhanced pore volume, increased porosity, and variable pore size, mesoporous materials, such as mesoporous silica and mesoporous carbon, have attracted significant attention in the areas of physical science and biomedical sciences. Due to their compositional and biological similarities to natural tissues, synthetic nanoscaled mesoporous hydroxyapatite (MPHA) nanoparticles possess good biocompatibility, bioactivity, and osteoconductivity and have recently expanded their applicability in a wide range of fields such as in tissue replacement, drug/gene delivery carriers, and biocompatible coatings. In this study, we defined a novel route to synthesize mesoporous hydroxyapatite nanoparticles by the sol-gel method in the presence of stearic acid (SA), a biocompatible medium chain fatty acid that would function as an organic modifier.
View Article and Find Full Text PDFA cost-effective, facile hydrothermal approach was made for the synthesis of SnO2/graphene (Gr) nano-composites. XRD diffraction spectra clearly confirmed the presence of tetragonal crystal system of SnO2 which was maintaining its structure in both pure and composite materials' matrix. The stretching and bending vibrations of the functional groups were analyzed using FTIR analysis.
View Article and Find Full Text PDFIn this research, a facile co-precipitation method was used to synthesize pure and Mg-doped ZnO nanoparticles (NPs). The structure, morphology, chemical composition, and optical and antibacterial activity of the synthesized nanoparticles (NPs) were studied with respect to pure and Mg-doped ZnO concentrations (0-7.5 molar (M) %).
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