Advanced spectroscopic approach for exploring the structural, optical, and electronic properties in dye-functionalized chitosan biopolymers.

This study employed advanced spectroscopic techniques to investigate the structural and optical properties of chitosan (CS) biopolymer films modified with natural dyes from Cosmos Sulphureus Cav. (CSC) flowers. FTIR results indicated that the inclusion of CSC dyes led to broader absorbance and decreased transmittance.

Bessel statistical convergence: New concepts and applications in sequence theory.

This research introduces novel concepts in sequence theory, including Bessel convergence, Bessel boundedness, Bessel statistical convergence, and Bessel statistical Cauchy sequences. These concepts establish new inclusion relations and related results within mathematical analysis. Additionally, we extend the first and second Korovkin-type approximation theorems by incorporating Bessel statistical convergence, providing a more robust and comprehensive framework than existing results.

Patient Participant Perspectives on Implementation of Long-Acting Cabotegravir and Rilpivirine: Results From the Cabotegravir and Rilpivirine Implementation Study in European Locations (CARISEL) Study.

Introduction: CARISEL is an implementation-effectiveness "hybrid" study examining the perspectives of people living with HIV-1 (patient study participants [PSPs]) on cabotegravir (CAB) plus rilpivirine (RPV) long-acting (LA) dosed every 2 months (Q2M) across 5 European countries.

Methods: PSPs completed questionnaires on acceptability (Acceptability of Intervention Measure), appropriateness (Intervention Appropriateness Measure), and feasibility (Feasibility of Intervention Measure) at their first (Month [M] 1), third (M4), and seventh (M12) injection visits. Semistructured qualitative interviews were also conducted.

Cerebellar Haemorrhage After Corrective Surgery for Scoliosis in a Girl with Arrested Hydrocephalus.

A 14-year-old girl with congenital hydrocephalus and early-onset scoliosis presented with sudden onset of severe headache on the fourth postoperative day of scoliosis correction (definitive fusion). On evaluation, she was found to have cerebellar haemorrhage on computed tomography scan with the findings of obstructive hydrocephalus. Posterior fossa bleed with hydrocephalus contributing to raised ICP was suspected initially.

Switch to long-acting cabotegravir and rilpivirine in virologically suppressed adults with HIV in Africa (CARES): week 48 results from a randomised, multicentre, open-label, non-inferiority trial.

Background: Long-acting injectable cabotegravir and rilpivirine is licensed for individualised treatment of HIV-1 infection in resource-rich settings. Additional evidence is required to support use in African treatment programmes where demographic factors, viral subtypes, previous treatment, and delivery and monitoring approaches differ. The aim of this study was to determine whether switching to long-acting therapy with injections every 8 weeks is non-inferior to daily oral therapy in Africa.

Effects of the COVID-19 Infection on Women's Menstrual Cycle: A Retrospective Study at Latifa Hospital, Dubai, United Arab Emirates.

Background The COVID-19 pandemic has affected all of us in one way or another. The menstrual cycle is a reflection of the female reproductive system, and it is influenced by various factors including stress and infections. Although there is little information available about how the COVID-19 pandemic has affected women's reproductive health, it has had a significant impact on women.

Outcomes of the Expectant Management of 10 Cesarean Scar Pregnancy Cases in Patients Who Refused the Termination of Pregnancy.

Objective: Expectant management of cesarean scar pregnancy (CSP) in patients who refuse termination of pregnancy and continue with placenta accreta spectrum (PAS) is possible with multidisciplinary care and careful monitoring in a tertiary care center. Doctors with the relevant expertise in managing PAS use highly accurate ultrasound as a tool to diagnose, monitor, and manage this disorder, which enables them to determine appropriate surgical strategies and techniques to achieve optimum maternal and fetal outcomes with minimal blood loss and no major maternal mortality and morbidity. In this study, we aim to evaluate expectant management in such patients.

Perceptions of Obstetrics/Gynecology Surgeons on Non-medically Indicated Cesarean Sections: A Cross-Sectional Study.

Background: Numerous factors can influence decisions regarding the type of delivery of human babies. There is an increasing demand for non-medically indicated cesarean sections (CS) (non-miCS) or CS on request (CSor). Therefore, this survey study aimed to identify the factors that may foster the decision of CS among obstetricians.

PTSS in COVID-19 survivors peritraumatic stress symptoms among COVID-19 survivors in Iraq.

The COVID-19 pandemic became a source of psychological distress worldwide. People infected with the disease faced the possibility of losing their lives, and due to the high number of people with the disease, hospitals were overburdened. Therefore, the situation had characteristics of a traumatic event; this is especially true in Iraq since the healthcare system is on the brink of failure, and the hospitals are a place of low-quality service.

Variation in the Optical Properties of PEO-Based Composites via a Green Metal Complex: Macroscopic Measurements to Explain Microscopic Quantum Transport from the Valence Band to the Conduction Band.

In this study, a green chemistry method was used to synthesize polymer composites based on polyethylene oxide (PEO). The method of the remediation of metal complexes used in this study is an environmentally friendly procedure with a low cost. Zinc metal ion (Zn)-polyphenol (PPHNL) complexes were synthesized for two minutes via the combination of a black tea leaf (BTL) extract solution with dissolved Zn-acetate.

Thermal boundary layer analysis of MHD nanofluids across a thin needle using non-linear thermal radiation.

An analysis of steady two-dimensional boundary layer MHD (magnetohydrodynamic) nanofluid flow with nonlinear thermal radiation across a horizontally moving thin needle was performed in this study. The flow along a thin needle is considered to be laminar and viscous. The Rosseland estimate is utilized to portray the radiation heat transition under the energy condition.

The Diagnosis of Normocalcaemic Hyperparathyroidism is Strikingly Dissimilar Using Different Commercial Laboratory Assays.

We assessed the impact of intact parathyroid hormone (iPTH) and adjusted calcium analyses on Abbott, Roche and Siemens analytical platforms in the diagnosis of normocalcaemic primary hyperparathyroidism (NCPHPT). These assays are used by over 85% of clinical laboratories in the UK. Over five months, consecutive serum samples from outpatients with NCPHPT in the laboratory with Abbott assays were identified, aliquoted and stored at -80°C.

Analytical results for positivity of discrete fractional operators with approximation of the domain of solutions.

We study the monotonicity method to analyse nabla positivity for discrete fractional operators of Riemann-Liouville type based on exponential kernels, where $ \left({}_{{c_0}}^{C{F_R}}\nabla^{\theta} \mathtt{F}\right)(t) > -\epsilon\, \Lambda(\theta-1)\, \bigl(\nabla \mathtt{F}\bigr)(c_{0}+1) $ such that $ \bigl(\nabla \mathtt{F}\bigr)(c_{0}+1)\geq 0 $ and $ \epsilon > 0 $. Next, the positivity of the fully discrete fractional operator is analyzed, and the region of the solution is presented. Further, we consider numerical simulations to validate our theory.

Positivity and monotonicity results for discrete fractional operators involving the exponential kernel.

This work deals with the construction and analysis of convexity and nabla positivity for discrete fractional models that includes singular (exponential) kernel. The discrete fractional differences are considered in the sense of Riemann and Liouville, and the υ-monotonicity formula is employed as our initial result to obtain the mixed order and composite results. The nabla positivity is discussed in detail for increasing discrete operators.

New classifications of monotonicity investigation for discrete operators with Mittag-Leffler kernel.

This paper deals with studying monotonicity analysis for discrete fractional operators with Mittag-Leffler in kernel. The $ \nu- $monotonicity definitions, namely $ \nu- $(strictly) increasing and $ \nu- $(strictly) decreasing, are presented as well. By examining the basic properties of the proposed discrete fractional operators together with $ \nu- $monotonicity definitions, we find that the investigated discrete fractional operators will be $ \nu^2- $(strictly) increasing or $ \nu^2- $(strictly) decreasing in certain domains of the time scale $ \mathbb{N}_a: = \{a, a+1, \dots\} $.

Fuzzy-interval inequalities for generalized preinvex fuzzy interval valued functions.

In this paper, firstly we define the concept of -preinvex fuzzy-interval-valued functions (-preinvex FIVF). Secondly, some new Hermite-Hadamard type inequalities (- type inequalities) for -preinvex FIVFs via fuzzy integrals are established by means of fuzzy order relation. Finally, we obtain Hermite-Hadamard Fejér type inequalities (- Fejér type inequalities) for -preinvex FIVFs by using above relationship.

Fuzzy integral inequalities on coordinates of convex fuzzy interval-valued functions.

In this study, we introduce and study new fuzzy-interval integral is known as fuzzy-interval double integral, where the integrand is fuzzy-interval-valued functions (FIVFs). Also, some fundamental properties are also investigated. Moreover, we present a new class of convex fuzzy-interval-valued functions is known as coordinated convex fuzzy-interval-valued functions (coordinated convex FIVFs) through fuzzy order relation (FOR).

Partial myocutaneous gluteal flap for perineal reconstruction of extralevator abdominoperineal defects. A single surgeon series of 49 cases in 8 years, and a modification of the technique.

Introduction: Extralevator abdominoperineal excision (ELAPE) for low rectal tumours necessitates a reliable method of reconstructing the perineum. The senior author developed the partial myocutaneous gluteal (PMG) flap. We present 49 consecutive reconstructions with the refinement of the original procedure.

Biochemical assessment of adequate levothyroxine replacement in primary hypothyroidism differs with different TSH assays: potential clinical implications.

Aim: Thyroid stimulating hormone (TSH) assays provided by Abbott Laboratories and Roche Diagnostics are used by approximately 75% of laboratories in the UK. We assessed the potential impact of Abbott and Roche TSH assay differences on the biochemical assessment of levothyroxine replacement in primary hypothyroidism.

Method: Samples from 100 consecutive primary care patients (83 women, median age 64 years, IQR 51-73 years) with primary hypothyroidism on adequate levothyroxine based on an Abbott Architect TSH in the reference range were analysed for TSH on Roche cobas within 24 hours.

The diagnosis and management of subclinical hypothyroidism is assay-dependent- Implications for clinical practice.

Objective: We assessed the commutativity of Roche and Abbott thyroid assays in the diagnosis and management of subclinical hypothyroidism (SCH). The Roche and Abbott thyroid assays are used by approximately 75% of clinical laboratories in the UK.

Method: Consecutive samples received from primary care on patients with SCH who had a raised thyroid-stimulating hormone (TSH) <10 mIU/L and a normal free thyroxine (fT4) from two laboratories using either Roche or Abbott thyroid assays were identified over 10 working days.

Biotin immunoassay interference: A UK-based prevalence study.

Background: Biotin interference in biotin-streptavidin-based immunoassays is increasingly reported due to individuals taking biotin-containing supplements and patients prescribed biotin. The reported prevalence of serum biotin above the lowest threshold (≥10 g/L) for interference in Roche Diagnostics immunoassay tests is 0.8% in Australia and 7.