Publications by authors named "Mohammed Hachemaoui"

In this study, four adsorbents were developed: layered silicate magadiite material (mag), Hexadecyltrimethylammonium intercalated magadiite (HDTMA@mag), a cross-linked composite of sodium alginate and magadiite (ALG@mag) and a cross-linked composite of sodium alginate and HDTMA@magadiite (ALG@HDTMA@mag). The adsorbents were evaluated for their effectiveness in removing of Methylene Blue (MB) and Eriochrome Black T (EBT) dyes. The prepared adsorbents were characterized using SEM, XRD, FTIR, and zeta potential measurements.

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Biodegradable and very low-cost adsorbent beads were prepared from date pits powder (DP) and sodium alginate (SA). DP to SA ratios was varied (1/2, 1/4 and 1/6) and used to eliminate Crystal violet (CV) a cationic dye. Adsorbents were characterized by FTIR, SEM-EDS, UV-vis DR, TGA and the point of zero charge (pH).

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This work focuses on the preparation of composite beads from alginate crosslinked with copper at several loading percent and also loaded with ZnNPs. Th obtained samples were applied as catalysts for the reduction of the organic polluants 4-NP, MB, OG, MO, and CR in simple and binary systems. XRD results and TEM images confirmed the presence of ZnNPs in the polymer matrix.

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Nickel oxide nanoparticles supported activated carbon (AC-NiO) was fabricated using thermal activation. Then, AC-NiO composite was immobilized on alginate beads to obtain 3-dimensional network structure ALG@AC-NiO nanocomposite beads for catalytic reduction of Congo red (CR) dye. The resulting nanocomposite beads were identified by various physical techniques.

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Article Synopsis
  • The mesoporous silica MCM-41 was synthesized and modified with silver and copper for use as antibacterial/antifungal agents and catalysts to reduce various dyes like Methylene Blue and Congo Red.
  • The catalysts were thoroughly characterized, revealing that calcination led to well-distributed copper oxide and silver nanoparticles, which significantly influenced their catalytic activity and efficiency in dye reduction.
  • The Ag-Cu-MCM(0.05) catalyst exhibited the highest activity, especially in single-dye systems, and showed improved selectivity for Methylene Blue in binary systems, while uncalcined materials demonstrated superior antibacterial and antifungal properties due to the synergy between copper and silver species.
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This work focuses on the preparation of aerogel composite beads based on Zn(II)-crosslinked alginate and loaded with different percentages of AgNPs using a simple approach. The obtained samples were evaluated in two different applications: the first application consists in their use as catalysts for the reduction of MB, MO, OG and CR dyes in a simple and binary system under the presence of NaBH. For this, several parameters affecting the catalytic behavior of these catalysts have been investigated and discussed such as the catalyst mass, AgNPs content, dye nature, and the selectivity of the catalyst in a binary system.

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In this paper, a new family of composite materials was prepared based on calcium alginate and metal nanoparticle-loaded zeolite omega. Different types of metal nanoparticles (MNPs), namely Cu, Co and Fe, were loaded onto zeolite omega to test the performance of the resulting metal/zeolite@alginate composites towards the catalytic reduction of methylene blue dye. To examine their application field as broadly as possible, these composite beads were also tested as antibacterial and antifungal agents against several types of bacteria.

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This work concerns the preparation of composite beads based on calcium alginate and FeO@MCM-41. In the first step, the material FeO@MCM-41 was prepared mechanically using several FeO contents, then was encapsulated by calcium alginate as a cross-linking matrix to give the composites MC@CA(x). The composite beads were used as catalysts for the reduction of MB and OG dyes in a simple system.

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Unilateral labyrinthectomy results in oculomotor and postural disturbances that regress in a few days during vestibular compensation. The long-term (after 1 mo) consequences of unilateral labyrinthectomy were investigated by characterizing the static and dynamic membrane properties of the ipsilesional vestibular neurons recorded intracellularly in guinea pig brain stem slices. We compared the responses of type A and type B medial vestibular nucleus neurons identified in vitro to current steps and ramps and to sinusoidal currents of various frequencies.

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In the guinea pig, in the absence of any stimulation, all the neurons of the vestibular nuclei are tonically firing. After an ipsilateral labyrinthectomy, these neurons first cease to fire but recover their previous discharge in 7 days. Here, we tested whether a modification of the spike generator, the process transforming synaptic currents into spike patterns, could be a factor underlying this restoration.

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