Polyaniline-magnesia (PANI/MgO) composites with a fibrous nanostructure were synthesized via in situ oxidative polymerization, enabling uniform MgO integration into the polyaniline matrix. These composites were characterized using FTIR spectroscopy to analyze intermolecular bonding, XRD to assess crystallographic structure and phase purity, and SEM to examine surface morphology and topological features. The resulting PANI/MgO nanofibers were utilized to develop ammonia (NH) gas-sensing probes with evaluations conducted at room temperature.
View Article and Find Full Text PDFStructural health monitoring (SHM) is crucial for maintaining concrete infrastructure. The data collected by these sensors are processed and analyzed using various analysis tools under different loadings and exposure to external conditions. Sensor-based investigation on concrete has been carried out for technologies used for designing structural health monitoring sensors.
View Article and Find Full Text PDFWe demonstrate for the first time the combination of two additive manufacturing technologies used in tandem, fused deposition modelling (FDM) and melt electrowriting (MEW), to increase the range of possible MEW structures, with a focus on creating branched, hollow scaffolds for vascularization. First, computer-aided design (CAD) was used to design branched mold halves which were then used to FDM print conductive polylactic acid (cPLA) molds. Next, MEW was performed over the top of these FDM cPLA molds using polycaprolactone (PCL), an FDA-approved biomaterial.
View Article and Find Full Text PDFIntoxication with methanol most commonly occurs as a consequence of ingesting, inhaling, or coming into contact with formulations that include methanol as a base. Clinical manifestations of methanol poisoning include suppression of the central nervous system, gastrointestinal symptoms, and decompensated metabolic acidosis, which is associated with impaired vision and either early or late blindness within 0.5-4 h after ingestion.
View Article and Find Full Text PDFFused deposition modeling (FDM), one of the most widely used additive manufacturing (AM) processes, is used for fabrication of 3D models from computer-aided design data using various materials for a wide scope of applications. The principle of FDM or, in general, AM plays an important role in minimizing the ill effects of manufacturing on the environment. Among the various available reinforcements, short glass fiber (SGF), one of the strong reinforcement materials available, is used as a reinforcement in the acrylonitrile butadiene styrene (ABS) matrix.
View Article and Find Full Text PDFMelt extrusion 3D printing has become an attractive additive manufacturing technology to construct degradable scaffolds as tissue precursors in order to create clinically relevant medical devices. Towards this end, a commonly used synthetic polyester, poly-caprolactone (PCL), was used to make scaffolds composed of different biomaterial compositions to increase bioactivity using 3D melt pneumatic extrusion technology. Varying ratios of the natural biopolymer, chitosan, or the bioceramic, β-tricalcium phosphate (TCP) were blended with PCL to fabricate support scaffolds with three-dimensional (3D) architecture for human bone-marrow derived mesenchymal stem cell (hBMSC) growth for potential bone regeneration application.
View Article and Find Full Text PDF