Synthesis, Characterization, and Toxicity Assessment of Zinc Oxide-Doped Manganese Oxide Nanoparticles in a Macrophage Model.

The doping of engineered nanomaterials (ENMs) is a key tool for manipulating the properties of ENMs (e.g., electromagnetic, optical, etc.

Green, Solvent-Free Mechanochemical Synthesis of Nano AgO/MnO/N-Doped Graphene Nanocomposites: An Efficient Catalyst for Additive-Base-Free Aerial Oxidation of Various Kinds of Alcohols.

Herein, we report a solvent-less, straightforward, and facile mechanochemical technique to synthesize nanocomposites of AgO nanoparticles-doped MnO, which is further codoped with nitrogen-doped graphene (N-DG) [i.e., (X %)N-DG/MnO-(1% AgO)] using physical milling of separately prepared N-DG and AgO NPs-MnO annealed at 400 °C over an eco-friendly ball-mill process.

Improved eco-friendly CsSnGeI perovskite photovoltaic efficiency beyond 20% with SMe-TATPyr hole-transporting layer.

Perovskites composed of inorganic cesium (Cs) halide provide a route to thermally resistant solar cells. Nevertheless, the use of hole-transporting layers (HTLs) with hydrophobic additives is constrained by moisture-induced phase deterioration. Due to significant electrical loss, dopant-free HTLs are unable to produce practical solar cells.

Kinetic and equilibrium study of graphene and copper oxides modified nanocomposites for metal ions adsorption from binary metal aqueous solution.

Presently, the main cause of pollution of natural water resources is heavy metal ions. The removal of metal ions such as nickel (Ni) and cadmium (Cd) has been given considerable attention due to their health and environmental risks. In this regard, for wastewater treatment containing heavy metal ions, graphene oxide (GO) nanocomposites with metal oxide nanoparticles (NPs) attained significant importance.

Sunlight mediated removal of toxic pollutants from Yamuna wastewater using efficient nano TeO-ZnO nanocomposites.

We have utilised our TeO-ZnO nanocomposites for Yamuna wastewater treatment in natural sunlight wherein the sampling site was Nigam Bodh Ghat, Kashmere Gate, Delhi. In BET isotherm, TZ NCs exhibited type IV isotherm forming a H3 like hysteric loop sustaining mesoporous characteristic with an increase in surface area, pore volume and pore diameter of 56.76 m/g, 0.

Polymer Backbone Stabilized Methylammonium Lead Bromide Perovskite Nano Islands.

Organic-inorganic hybrid perovskite materials continue to attract significant interest due to their optoelectronic application. However, the degradation phenomenon associated with hybrid structures remains a challenging aspect of commercialization. To overcome the stability issue, we have assembled the methylammonium lead bromide nano islands (MNIs) on the backbone of poly-3-dodecyl-thiophene (PDT) for the first time.

Preparation of coated MgFe layered double hydroxide nanoparticles on cement kiln dust and intercalated with sodium dodecyl sulfate as an intermediate layer for the adsorption of estrogen from water.

Estrogenic hormones, found as micropollutants in water systems, give rise to grave concerns for human health and marine ecosystems, triggering a cascade of adverse effects. This research presents an innovative manufacturing approach using nanoscale layered double hydroxides of magnesium and iron, with sodium dodecyl sulfate surfactant, to create highly efficient sorbent cement kiln dust (CKD) based beads (CKD/MgFe-SDS-LDH-beads). These beads effectively remove estrone from water.

Morphology Controlled Deposition of Vanadium Oxide (VO) Nanoparticles on the Surface of Highly Reduced Graphene Oxide for the Photocatalytic Degradation of Hazardous Organic Dyes.

Semiconducting nanomaterials based heterogeneous photocatalysis represent a low-cost, versatile technique for environmental remediation, including pollution mitigation, energy management and other environmental aspects. Herein, we demonstrate the syntheses of various heterogeneous photocatalysts based on highly reduced graphene oxide (HRG) and vanadium oxide (VO)-based nanocomposites (HRG-VO). Different shapes (rod, sheet and urchin forms) of VO nanoparticles were successfully fabricated on the surface of HRG under solvo-/hydrothermal conditions by varying the amount of water and ethanol.

Microstructure and Oxygen Evolution Property of Prussian Blue Analogs Prepared by Mechanical Grinding.

Solvent-free mechanochemical synthesis of efficient and low-cost double perovskite (DP), like a cage of Prussian blue (PB) and PB analogs (PBAs), is a promising approach for different applications such as chemical sensing, energy storage, and conversion. Although the solvent-free mechanochemical grinding approach has been extensively used to create halide-based perovskites, no such reports have been made for cyanide-based double perovskites. Herein, an innovative solvent-free mechanochemical synthetic strategy is demonstrated for synthesizing Fe[Fe(CN)], Co[Fe(CN)], and Ni[Fe(CN)], where defect sites such as carbon-nitrogen vacancies are inherently introduced during the synthesis.

Effectiveness of Nonfunctionalized Graphene Oxide Nanolayers as Nanomedicine against Colon, Cervical, and Breast Cancer Cells.

Recent studies in nanomedicine have intensively explored the prospective applications of surface-tailored graphene oxide (GO) as anticancer entity. However, the efficacy of nonfunctionalized graphene oxide nanolayers (GRO-NLs) as an anticancer agent is less explored. In this study, we report the synthesis of GRO-NLs and their in vitro anticancer potential in breast (MCF-7), colon (HT-29), and cervical (HeLa) cancer cells.

Surface-coated magnetic nanostructured materials for robust bio-catalysis and biomedical applications-A review.

Background: Enzymes based bio-catalysis has wide range of applications in various chemical and biological processes. Thus, the process of enzymes immobilization on suitable support to obtain highly active and stable bio-catalysts has great potential in industrial applications. Particularly, surface-modified magnetic nanomaterials have garnered a special interest as versatile platforms for biomolecules/enzyme immobilization.

Pyrene Functionalized Highly Reduced Graphene Oxide-palladium Nanocomposite: A Novel Catalyst for the Mizoroki-Heck Reaction in Water.

The formation of a C-C bond through Mizoroki-Heck cross-coupling reactions in water with efficient heterogeneous catalysts is a challenging task. In this current study, a highly reduced graphene oxide (HRG) immobilized palladium (Pd) nanoparticle based catalyst (HRG-Py-Pd) is used to catalyze Mizoroki-Heck cross-coupling reactions in water. During the preparation of the catalyst, amino pyrene is used as a smart functionalizing ligand, which offered chemically specific binding sites for the effective and homogeneous nucleation of Pd NPs on the surface of HRG, which significantly enhanced the physical stability and dispersibility of the resulting catalyst in an aqueous medium.

Green Synthesized ZnO Nanoparticles as Biodiesel Blends and Their Effect on the Performance and Emission of Greenhouse Gases.

Pollution and global warming are a few of the many reasons for environmental problems, due to industrial wastes and greenhouse gases, hence there are efforts to bring down such emissions to reduce pollution and combat global warming. In the present study, zinc oxide nanoparticles are green synthesized using cow dung as fuel, through combustion. Synthesized material was characterized by FTIR, XRD, UV, and FESEM.

Photocatalytic Degradation of Cefixime Trihydrate by Bismuth Ferrite Nanoparticles.

The present work was carried out to synthesize bismuth ferrite (BFO) nanoparticles by combustion synthesis, and to evaluate the photocatalytic activity of synthesized bismuth ferrite nanoparticles against cefixime trihydrate. BFO nanoparticles were successfully synthesized using bismuth (III) nitrate and iron (III) nitrate by a combustion synthesis method employing different types of fuels such as maltose, succinic acid, cinnamic acid, and lactose. The effects of the different types of fuels on the morphology and size of the bismuth ferrite nanoparticles were investigated.

Electrocatalytic detection of noxious antioxidant diphenylamine in fruit samples with support of Cu@nanoporous carbon modified sensor.

Herein, the facile synthesis of copper(II) and benzene-1,3,5-tricarboxylate (Cu-BTC) and copper nanoporous carbon (Cu@NPC) for the electrochemical detection of diphenylamine (DPA) was systematically investigated. The Cu-BTC and Cu@NPC materials structural, morphological, and thermal stability were evaluated and confirmed using FE-SEM, HR-TEM, XRD, FT-IR, and TGA. The electrocatalytic behavior of sensor materials was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV).

Nanotextured Soft Electrothermo-Pneumatic Actuator for Constructing Lightweight, Integrated, and Untethered Soft Robotics.

In this study, we fabricated a nanofiber-based electrothermo-pneumatic soft actuator (ETPSA) using electrospinning technique. The actuator uses liquid-vapor phase transition. The ETPSA developed in the present study goes beyond the limitations of the existing pneumatic soft actuators.

Biocatalytic degradation of organophosphate pesticide from the wastewater and hydrolytic enzyme properties of consortium isolated from the pesticide contaminated water.

The indiscriminate application of various pesticides leads to toxicity to the humans, animals, fishes and threatens the environment and ecosystem. The present study was aimed to investigate pesticide degrading bacteria from the pesticide contaminated sample and to localize organophophate hydrolase activity from the bacteria. Sediment sample was selected as the source of microorganism for the degradation of chlorpyrifos.

Knowledge extraction of sonophotocatalytic treatment for acid blue 113 dye removal by artificial neural networks.

Removing decolorizing acid blue 113 (AB113) dye from textile wastewater is challenging due to its high stability and resistance to removal. In this study, we used an artificial neural network (ANN) model to estimate the effect of five different variables on AB113 dye removal in the sonophotocatalytic process. The five variables considered were reaction time (5-25 min), pH (3-11), ZnO dosage (0.

Plant-Mediated Zinc Oxide Nanoparticles: Advances in the New Millennium towards Understanding Their Therapeutic Role in Biomedical Applications.

Zinc oxide nanoparticles have become one of the most popular metal oxide nanoparticles and recently emerged as a promising potential candidate in the fields of optical, electrical, food packaging, and biomedical applications due to their biocompatibility, low toxicity, and low cost. They have a role in cell apoptosis, as they trigger excessive reactive oxygen species (ROS) formation and release zinc ions (Zn) that induce cell death. The zinc oxide nanoparticles synthesized using the plant extracts appear to be simple, safer, sustainable, and more environmentally friendly compared to the physical and chemical routes.

Reinforcing the tetracene-based two-dimensional CH sheet by decorating the Li, Na, and K atoms for hydrogen storage and environmental application -A DFT study.

To meet the increasing need of energy resources, hydrogen (H) is being considered as a promising candidate for energy carrier that has motivated research into appropriate storage materials among scientists. Thus, in this study for the first time, zig-zag and armchair edged tetracene based porous carbon sheet (CH) is investigated for H storage using the density functional theory. To explore the hydrogen storage capacity, the hydrogen molecule is initially positioned parallel to the CH sheet at three different sites, resulting in lower adsorption energies of -0.

Environmental photochemistry with Sn/F simultaneously doped TiO nanoparticles: UV and visible light induced degradation of thiazine dye.

Environmental route such as degradation of toxic dyes can be improved through photochemical activity such as light driven photocatalytic degradation. Herein, fluorine and tin simultaneously doped TiO nanoparticles were synthesized and characterized. The formation of anatase phase in synthesized samples and the reduction in the crystallite size of doped TiO was confirmed from XRD results.

Sol-Gel Synthesis of Dy-Substituted NiCuZn(FeDy)O Nano Spinel Ferrites and Evaluation of Their Antibacterial, Antifungal, Antibiofilm and Anticancer Potentialities for Biomedical Application.

Background: The constant rise of microbial biofilm formation and drug resistance to existing antimicrobial drugs poses a significant threat to community health around the world because it reduces the efficacy and efficiency of treatments, increasing morbidity, mortality, and health-care expenditures. As a result, there is an urgent need to develop novel antimicrobial agents that inhibit microbial biofilm formation.

Methods: The [NiCuZn](FeDy)O(x≤0.

Straightforward Synthesis of MnO/ZnO/EuO-Based Ternary Heterostructure Nano-Photocatalyst and Its Application for the Photodegradation of Methyl Orange and Methylene Blue Dyes.

Zinc oxide-ternary heterostructure MnO/ZnO/EuO nanocomposites were successfully prepared via waste curd as fuel by a facile one-pot combustion procedure. The fabricated heterostructures were characterized utilizing XRD, UV-Visible, FT-IR, FE-SEM, HRTEM and EDX analysis. The photocatalytic degradation efficacy of the synthesized ternary nanocomposite was evaluated utilizing model organic pollutants of methylene blue (MB) and methyl orange (MO) in water as examples of cationic dyes and anionic dyes, respectively, under natural solar irradiation.

Counteraction of Biofilm Formation and Antimicrobial Potential of Functionalized Silver Nanoparticles against and Multidrug-Resistant Gram-Negative and Gram-Positive Bacteria.

Biofilms not only protect bacteria and Candida species from antibiotics, but they also promote the emergence of drug-resistant strains, making eradication more challenging. As a result, novel antimicrobial agents to counteract biofilm formation are desperately needed. In this study, leaf extract (TCE) was used to optimize the TCE-capped silver nanoparticles (TCE-AgNPs) via a one-pot single-step method.