Enhanced photocatalytic activity of nano-silica/copper plasmon by aminofunctional silane for dye pollutant degradation.

The synthesis of silica gel nanostructures and loading it with copper specie via a hydrothermal process were performed. The sample is treated with an amino-functional reagent 3-aminopropyl triethoxysilane (APTES). The products were characterized by X-ray diffraction (XRD), FT-IR, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), TGA/DSC measurements, and X-ray photoelectron spectroscopy (XPS).

Hollow fiber liquid-phase microextraction based on the use of a rotating extraction cell: A green approach for trace determination of rhodamine 6G and methylene blue dyes.

In this work, a novel mode of hollow fiber liquid-phase microextraction (HF-LPME) technique namely rotating extraction cell solvent bar microextraction (REC-SBME) was introduced. The proposed method was applied for the preconcentration of methylene blue (MB) and rhodamine 6G (RG) in some real samples, including soft drink, lipstick, environmental water, and wastewater samples. In the extraction setup, two pieces of hollow fibers were fixed on a mechanical support and immersed in a rotating extraction cell containing the sample solution during the extraction process.

Solvent stir bar microextraction technique with three-hollow fiber configuration for trace determination of nitrite in river water samples.

In this work, trace determination of nitrite in river water samples was studied using solvent stir bar microextraction system with three-hollow fiber configuration (3HF-SSBME) as a preconcentration step prior to UV-Vis spectrophotometry. The obtained results showed that the increase in the number of solvent bars can improve the extraction performance by increasing the contact area between acceptor and sample solutions. The extraction process relies on the well-known oxidation-reduction reaction of nitrite with iodide excess in acidic donor phase to form triiodide, and then its extraction into organic acceptor phase using a cationic surfactant.

A four-hollow fibers geometry of revolving solvent bar microextraction setup for the enrichment of trace ammonia.

In this work, for the first time, a revolving solvent bar microextraction (RSBME) system was introduced as an efficient alternative method to conventional SBME. The setup proposed for RSBME provides a stable and repeatable method to increase the preconcentration factor. In order to provide the maximum extraction capacity of the organic acceptor phase, four-hollow fibers were applied.

Trace Determination of Iron in Real Waters and Fruit Juice Samples Using Rapid Method: Optimized Dispersive Liquid-Liquid Microextraction with Synthesized Nontoxic Chelating Agent.

The purpose of this research was to optimize a new method for preconcentration and determination of trace iron concentrations in aqueous solutions. For this purpose, a newly synthesized ligand, 3-(3-hydroxy-2-methyl-4-oxopyridin-1(4H)-yl) benzoic acid (3-OH-3-MOPBA), was used in the dispersive liquid-liquid microextraction (DLLME) method coupled with UV-vis spectroscopy. The experiments considering input variables of extractant volume, disperser volume, salt concentration, and pH were designed with the aid of central composite design (CCD).

Optimization of a methodology for determination of iron concentration in aqueous samples using a newly synthesized chelating agent in dispersive liquid-liquid microextraction.

The aim of this study was to establish a new dispersive liquid-liquid microextraction (DLLME) technique for the determination of iron concentration in aqueous solutions and fruit juices based on the reaction between iron and 3-hydroxy-1-(3-hydroxyphenyl)-2-methylpyridin-4(1H)-one (3-OH-PMPO) as a chelating agent. A central composite design (CCD) was applied to optimize the effects of independent parameters (pH, volume of disperser solvent and extractant solvent and chelating agent concentration) on extraction efficiency. Under the optimized conditions, the analytical curve is linear in a concentration range of 10-750 μgL with a detection limit of 5 μgL.

Selective determination of caffeine in foods with 3D-graphene based ultrasound-assisted magnetic solid phase extraction.

An efficient method was applied for extraction of caffeine in food samples. Three-dimensional graphene-FeO (3D-G-FeO) nanoparticles was successfully synthesized and used as adsorbent in magnetic solid phase extraction (MSPE) step. The properties of synthesized adsorbent were characterized by fourier-transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), vibrating sample magnetometer (VSM), X-ray diffraction (XRD), Raman spectroscopy, Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) methods.

Ultrasonically assisted removal of Congo Red, Phloxine B and Fast green FCF in ternary mixture using novel nanocomposite following their simultaneous analysis by derivative spectrophotometry.

In this study dependency of simultaneous adsorption of Congo Red (CR), Phloxine B (BP) and Fast green FCF (FG) onto CuS/ZnS nanocomposites loaded on activated carbon (CuS/ZnS-NCs-AC) to pH, adsorbent mass, sonication time and initial dyes concentration were modeled and optimized, while CuS/ZnS-NCs-AC was identified by XRD, FESEM and EDS analysis. CR, PB and FG concentration determination were undertaken by first and second order derivative spectrophotometry in ternary mixture. According to central composite design (CCD) based on desirability function (DF), the best experimental conditions was set as pH 6.

The choice of ultrasound assisted extraction coupled with spectrophotometric for rapid determination of gallic acid in water samples: Central composite design for optimization of process variables.

A sensitive procedure namely ultrasound-assisted (UA) coupled dispersive nano solid-phase microextraction spectrophotometry (DNSPME-UV-Vis) was designed for preconcentration and subsequent determination of gallic acid (GA) from water samples, while the detailed of composition and morphology and also purity and structure of this new sorbent was identified by techniques like field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) and Energy-dispersive X-ray spectroscopy (EDX) techniques. Among conventional parameters viz. pH, amount of sorbent, sonication time and volume of elution solvent based on Response Surface Methodology (RSM) and central composite design according to statistics based contour the best operational conditions was set at pH of 2.

A new microplatform based on titanium dioxide nanofibers/graphene oxide nanosheets nanocomposite modified screen printed carbon electrode for electrochemical determination of adenine in the presence of guanine.

The current techniques for determining adenine have several shortcomings such as high cost, high time consumption, tedious pretreatment steps and the requirements for highly skilled personnel often restrict their use in routine analytical practice. This paper describes the development and utilization of a new nanocomposite consisting of titanium dioxide nanofibers (TNFs) and graphene oxide nanosheets (GONs) for screen printed carbon electrode (SPCE) modification. The synthesized GONs and TNFs were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR).

Photocatalytic activity of TiO₂ nanoparticles synthesized in presence of ammonium hexafluorosilicate.

A series of silicon incorporated TiO2 with anatase crystalline phase were prepared via sol-gel using ammonium hexafluorosilicate (AHFS). The synthesized products were characterized using X-ray diffraction, FTIR, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), UV-vis diffuse reflectance spectrophotometry (DRS), energy dispersive X-ray analysis (EDX) and BET surface area measurement. Presence of Si-O-Ti bonds is revealed based on the XPS results.

Lanthanum and zirconium co-doped ZnO nanocomposites: synthesis, characterization and study of photocatalytic activity.

Nanocomposits of zinc oxide co-doped with lanthanum and zirconium were prepared using the modified sol-gel method. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), diffuse reflectance spectroscopy (DRS), and BET surface area measurement. For comparison, the La and Zr mono doped ZnO have also been prepared under the same conditions.

MWCNTs/Cu(OH)2 nanoparticles/IL nanocomposite modified glassy carbon electrode as a voltammetric sensor for determination of the non-steroidal anti-inflammatory drug diclofenac.

This paper describes the development and utilization of a new nanocomposite consisting of Cu(OH)2 nanoparticles, hydrophobic ionic liquid 1-ethyl-3-methylimidazolium hexafluorophosphate (EMIMPF6) and multiwalled carbon nanotubes for glassy carbon electrode modification. The nanocomposite was characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM) along with energy-dispersive X-ray spectroscopy (EDX). The modified electrode was used for electrochemical characterization of diclofenac.

Ionic liquid-based dispersive liquid-liquid microextraction for the determination of formaldehyde in wastewaters and detergents.

Spectrophotometry in combination with ionic liquid-based dispersive liquid-liquid microextraction (DLLME) was applied for the extraction and determination of formaldehyde in real samples. The method is based on the reaction of formaldehyde with methyl acetoacetate in the presence of ammonia. The variation in the absorbance of the reaction product was measured at 375 nm.

A Fast Response Membrane Sensor based on Ethyl 1, 2, 3, 4-tetrahydro-6-methyl-4-phenyl-2-thioxopyrimidine-5-carboxylate for Detection of Lanthanum (III) Ions at Wide Concentration Range.

A PVC membrane La (III) ion-selective electrode has been constructed using ethyl1,2,3,4-tetrahydro-6-methyl-4-phenyl-2-thioxopyrimidine-5-carboxylate (ETMPTC) as a neutral ionophore. This electrode responds to La (III) ion with a sensitivity of 19.9 ± 0.