Physicochemical investigation of mercury sorption on mesoporous thioacetamide/chitosan from wastewater.

Mercury is a toxic environmental element, so it was necessary to prepare a new, highly efficient, cheap sorbent to remove it. A mesoporous thioacetamide/chitosan (MTA/CS) was manufactured via a simplistic strategy; the chitin deacetylation to gain chitosan (CS) and the addition of thioacetamide. The as-prepared MTA/CS was characterized using X-ray diffraction, EDX, SEM, FTIR, and BET surface analysis.

Characteristic Aspects of Uranium(VI) Adsorption Utilizing Nano-Silica/Chitosan from Wastewater Solution.

A new nano-silica/chitosan (SiO/CS) sorbent was created using a wet process to eliminate uranium(VI) from its solution. Measurements using BET, XRD, EDX, SEM, and FTIR were utilized to analyze the production of SiO/CS. The adsorption progressions were carried out by pH, SiO/CS dose, temperature, sorbing time, and U(VI) concentration measurements.

Selective Recovery of Cadmium, Cobalt, and Nickel from Spent Ni-Cd Batteries Using Adogen 464 and Mesoporous Silica Derivatives.

Spent Ni-Cd batteries are now considered an important source for many valuable metals. The recovery of cadmium, cobalt, and nickel from spent Ni-Cd Batteries has been performed in this study. The optimum leaching process was achieved using 20% HSO, solid/liquid (S/L) 1/5 at 80 °C for 6 h.

Synthesis of a New Chelating Iminophosphorane Derivative (Phosphazene) for U(VI) Recovery.

A new synthetic chelating N-hydroxy-N-trioctyl iminophosphorane (HTIP) was prepared through the reaction of trioctylphosphine oxide (TOPO) with N-hydroxylamine hydrochloride in the presence of a Lewis acid (AlCl). Specifications for the HTIP chelating ligand were successfully determined using many analytical techniques, C-NMR, H-NMR, FTIR, EDX, and GC-MS analyses, which assured a reasonable synthesis of the HTIP ligand. The ability of HTIP to retain U(VI) ions was investigated.

Cetylpyridinium Bromide/Polyvinyl Chloride for Substantially Efficient Capture of Rare Earth Elements from Chloride Solution.

A new sorbent cetylpyridinium bromide/polyvinylchloride (CPB/PVC) was prepared and tested to extract rare earth elements (REEs) from their chloride solutions. It was identified by FTIR, TGA, SEM, EDX, and XRD. The impact of various factors such as pH, RE ion initial concentration, contacting time, and dose amount via sorption process was inspected.

Rare Earth Group Separation after Extraction Using Sodium Diethyldithiocarbamate/Polyvinyl Chloride from Lamprophyre Dykes Leachate.

This study presents the first application of sodium diethyldithiocarbamate/polyvinyl chloride (DdTC/PVC) as a novel adsorbent for rare earth element (REE) sorption from leach liquors. DdTC/PVC has higher adsorption properties than other sorbents, the synthesis of DdTC/PVC is more accessible than other resins, and it is considered a more affordable sorbent. The three-liquid-phase extraction technique (TLPE) was applied to separate REEs into light, middle, and heavy rare earth elements as groups.

Inorganic-organic mesoporous hybrid segregators for selective and sensitive extraction of precious elements from urban mining.

This study aimed to develop a highly selective extraction protocol for gold (Au) ions from electronic urban waste (EUW) using simple, low-cost Inorganic-organic mesoporous hybrid segregators. The unique features of mesoporous hybrid segregator architectures are of particular to ensure effective adsorption system in terms of selective and sensitive recovery of Au ions from EUW. The segregator platform featured 3D micrometric, mesocage double-serrated plant-leaf-like γ-AlO sheets with hierarchy surfaces containing tri-modal mesopores interiorly and uniformly arranged toothed edges of ~20-40 and ~15 nm groove width and depth at the exterior surfaces, respectively.