Mechanisms governing the dissolution of phosphorus and iron in sewage sludge by the bioacidification process and its correlation with iron phosphate speciation.

In the last two decades, phosphorus (P) recovery from sewage sludge liquors gained much interest for its high-quality product potential. However, the consistently reported constraints are the low phosphorus availability and the technical-economical difficulties to increase it through chemical acidification. This article discusses the mechanisms of phosphorus dissolution by the biological acidification process (Biological acidification or acidic fermentation) as an alternative to chemical acidification.

Correlation between phosphorus removal technologies and phosphorus speciation in sewage sludge: focus on iron-based P removal technologies.

Phosphorus recovery from sewage sludge as secondary raw materials or as a direct P-rich fertiliser is one of the top frontrunner solutions to tackle Phosphorus (P) scarcity and depletion. However, the efficiency of this P recovery process greatly depends on its phosphorus dissolution potential, which in return relies on the phosphorus speciation in the sewage sludge. This article investigates the potential correlation between P speciation in sewage sludge and the iron-based P removal technologies used in sewage treatment plants (STP) through an innovative sequential extraction method based on the SEDEX method that distinguishes quantitatively between ferrous bound phosphate and ferric bound phosphate.