Biologically active Co (II), Cu (II), Zn (II) centered water soluble novel isoniazid grafted O-carboxymethyl chitosan Schiff base ligand metal complexes: Synthesis, spectral characterisation and DNA nuclease activity.

In this study, the new N, N, O tridentate donor water soluble isoniazid based biopolymer Schiff base ligand and their Co (II), Cu (II), Zn (II) metal complexes were prepared. The compounds were designed for potential biological application such as antibacterial, antifungal, anti-inflammatory, total antioxidant, antidiabetic and DNA binding studies. The synthesized compounds were illuminated in different light sources of various spectra were used to explore the functional groups of Biopolymer derivatives.

Synthesis and characterisation of novel Cu(ii)-anchored biopolymer complexes as reusable materials for the photocatalytic degradation of methylene blue.

This study focused on the synthesis, photocatalytic degradation of organic dyes and biological activity of novel N, N, O-donor tridentate water soluble 4-hydroxy benzohydrazide-grafted biopolymer Schiff base Cu(ii) complexes. The eco-friendly catalysts were designed for potential application in the degradation of organic dyes. The photocatalytic degradation of methylene blue was investigated with various irradiation times (30, 60, 90 and 120 min), catalytic dosages (5, 10, 15 and 20 mg) and pH (3, 7 and 12).

Fabrication of bioinspired chitosan/gelatin/allantoin biocomposite film for wound dressing application.

A biocomposite film composed of biopolymers chitosan (CS), gelatin (GE) and allantoin (AT) was fabricated by solution casting technique. The functional group interaction of the biocomposite films was inspected through the Attenuated total reflectance Fourier transform spectrometer (ATR-FTIR). The morphological changes and crystallinity of biocomposite films with varied ratios of chitosan/gelatin (CS/GE) and allantoin were examined under Scanning electron microscope (SEM) and X-ray diffractometer (XRD).

Biologically active novel N, N, O donor tridentate water soluble hydrazide based O-carboxymethyl chitosan Schiff base Cu (II) metal complexes: Synthesis and characterisation.

Water soluble hydrazide based O-carboxymethyl chitosan Schiff base ligands have been prepared from chitosan and a mixture of benzoic acidhydrazide with β-diketone by carboxymethylation using mono chloroaceticacid (MCA) through in-situ reaction. The degree of deacetylation of chitosan was determined by elemental analysis and potentiometric titration. Schiff base ligands and the functional groups were characterised by FT-IR, H, and C NMR spectroscopic techniques.