The exploration encompassed the synthesis and characterization of two innovative complexes, namely FePHNS and CuPHNS, employing a diverse array of analytical techniques such as elemental analysis, infrared and ultraviolet-visible spectroscopy, mass spectrometry, molar conductivity measurements, magnetic susceptibility assessments, and thermal analysis (TGA). In the spectral domain, infrared spectroscopy substantiated the tridentate ONS coordination of the PHNS ligand to the central metal atom. Thermal analysis offered valuable insights into the distribution and content of water molecules within the complexes.
View Article and Find Full Text PDFWe investigate the dynamics of non-classical correlations and quantum coherence in open quantum systems by employing metrics like local quantum Fisher information, local quantum uncertainty, and quantum Jensen-Shannon divergence. Our focus here is on a system of two qubits in two distinct physical situations: the first one when the two qubits are coupled to a cavity field whether the system is closed or open, while the second consists of two qubits immersed in dephasing reservoirs. Our study places significant emphasis on how the evolution of these quantum criterion is influenced by the initial state's purity (whether pure or mixed) and the nature of the environment (whether Markovian or non-Markovian).
View Article and Find Full Text PDFThe ligand 3-(-(2-hydroxyphenylimino) methyl)-4H-chromen-4-one (SL) has been synthesized and examined as a chemosensor for some metal ions in aqueous solutions based on colorimetric analysis. Color changes were monitored using UV-visible spectroscopy. Binding stoichiometry and limit of detection (LOD) were estimated using titration experimentation based on UV-visible absorbance and Job's plot.
View Article and Find Full Text PDFIn a system of two charge-qubits that are initially prepared in a maximally entangled Bell's state, the dynamics of quantum memory-assisted entropic uncertainty, purity, and negative entanglement are investigated. Isolated external cavity fields are considered in two different configurations: coherent-even coherent and even coherent cavity fields. For different initial cavity configurations, the temporal evolution of the final state of qubits and cavities is solved analytically.
View Article and Find Full Text PDFWe explore the non-local correlation dynamics in a Graphene sheet of disordered electrons in a two-dimensional honeycomb lattice, containing two sublattices, induced by the interaction range of impurity potentials of two Dirac points. The Bell function, uncertainty-induced non-locality, and concurrence are used to investigate the formation and robustness of the non-local correlation between the honeycomb lattice and the Dirac point. The generated lattice-point non-local correlations are explored when the lattice-point system is initially in the uncorrelated state.
View Article and Find Full Text PDFIn the thermodynamic equilibrium of dipolar-coupled spin systems under the influence of a Dzyaloshinskii-Moriya (D-M) interaction along the -axis, the current study explores the quantum-memory-assisted entropic uncertainty relation (QMA-EUR), entropy mixedness and the concurrence two-spin entanglement. Quantum entanglement is reduced at increased temperature values, but inflation uncertainty and mixedness are enhanced. The considered quantum effects are stabilized to their stationary values at high temperatures.
View Article and Find Full Text PDFAn analytical solution for a master equation describing the dynamics of a qubit interacting with a nonlinear Kerr-like cavity through intensity-dependent coupling is established. A superposition of squeezed coherent states is propped as the initial cavity field. The dynamics of the entangled qubit-cavity states are explored by negativity for different deformed function of the intensity-dependent coupling.
View Article and Find Full Text PDFNonclassical effects are investigated in a system formed by two quantum wells, each of which is inside an open cavity. The cavities are spatially separated, linked by a fiber, and filled with a linear optical medium. Based on Husimi distributions (HDs) and Wehrl entropy, we explore the effects of the physical parameters on the generation and the robustness of the mixedness and HD information in the phase space.
View Article and Find Full Text PDFWe explore the geometric phase in a system of two non-interacting qubits embedded in two separated open cavities linked via an optical fiber and leaking photons to the external environment. The dynamical behavior of the generated geometric phase is investigated under the physical parameter effects of the coupling constants of both the qubit-cavity and the fiber-cavity interactions, the resonance/off-resonance qubit-field interactions, and the cavity dissipations. It is found that these the physical parameters lead to generating, disappearing and controlling the number and the shape (instantaneous/rectangular) of the geometric phase oscillations.
View Article and Find Full Text PDFAn amendment to this paper has been published and can be accessed via a link at the top of the paper.
View Article and Find Full Text PDFWe explore the phase space quantum effects, quantum coherence and non-classicality, for two coupled identical qubits with intrinsic decoherence. The two qubits are in a nonlinear interaction with a quantum field via an intensity-dependent coupling. We investigate the non-classicality via the Wigner functions.
View Article and Find Full Text PDFNaunyn Schmiedebergs Arch Pharmacol
September 2020
Proliferation and apoptosis are two primary driving forces behind the pathogenesis of hepatocellular carcinoma (HCC). HCC is associated with Ki-67 and Bcl-2 overexpression, reduced Bax expression inducing disturbance of equilibrium between cellular proliferation and apoptosis, and exacerbated by reduced expression of PPAR-γ and FOXO-1. Our objective was to examine the mechanism by which the cyclic isoprenoid, β-ionone (βI), attenuated hepatocarcinogenesis and compare its possible anticancer activity with sorafenib (SF) as standard HCC treatment.
View Article and Find Full Text PDFWe explore the dissipative dynamics of two coupled qubits placed inside a coherent cavity-field under dipole-dipole interplay and 2-photon transitions. The generated non-classical correlations (NCCs) beyond entanglement are investigated via two measures based on the Hilbert-Schmidt norm. It is found that the robustness of the generated NCCs can be greatly enhanced by performing the intrinsic dissipation rate, dipole-dipole interplay rate, initial coherence intensity and the degree of the coherent state superpositions.
View Article and Find Full Text PDFOxidative and nitrosative stress-induced endothelial cell damage play an essential role in the pathogenesis of hepatic ischemia-reperfusion (IR) injury. IR is associated with reduced eNOS expression and exacerbated by superimposed stress. NOSTRIN induces intracellular endothelial nitric oxide synthase (eNOS) translocation and inducible nitric oxide synthase (iNOS) increases nitric oxide (NO) production.
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