The deployment of magnetically responsive and polymeric materials to remove dyes that are hazardous in aquatic environments has profoundly revolutionized environmental sustainability. This study focuses on removing the hazardous cationic Malachite Green (MG) dye from solutions, employing a novel magnetic composite film as an adsorbent, designated as AgCo FeO (ACFCeP). The composite was synthesized solvent casting, incorporating AgCo FeO nanoparticles and CeO into a cellulose acetate/polyvinylpyrrolidone (CA/PVP) polymer matrix.
View Article and Find Full Text PDFJ Electr Bioimpedance
January 2024
Bioimpedance measurements are becoming important in probing the human body for diagnosis and monitoring. An age old 4-electrode technique called tetrapolar impedance measurement (TPIM), giving transfer impedance, cannot localize a specific zone besides having large zones of negative sensitivity. A new technique named the focused impedance method (FIM) from Dhaka University (DU), Bangladesh used the algebraic average of two concentric and orthogonal TPIMs, localizing a zone of interest and having reduced magnitudes of negative sensitivity.
View Article and Find Full Text PDFIn this study, a novel gamma-ray radiation sensor has been developed depending on a 1D photonic crystal (1D-PhC). Based on porous silicon (PSi) layer that has been penetrated by a conjugated copolymer (B-co-MP) which consists of BEHP-PPV and MEH-PPV, with a fractional ratio of 60:40. The suggested method for the development of the dosimeter is based on the shift of photonic band-gap to shorter wavelengths, where exposure to gamma-ray radiation at doses ranging from 0 to 20 kGy alters the refractive index of the (B-co-MP) copolymer.
View Article and Find Full Text PDFFeO nanoparticles were embedded within a glauconite‑calcium alginate (G/CA) matrix to create magnetic hybrid spheres (MNPs-G/CA), with the aim of purifying water from methylene blue (MB) at temperatures of 25, 40, and 50 °C. MNPs-G/CA adsorbent was characterized using numerous techniques, including elemental mapping, zeta potential, FTIR, FESEM, XRD, EDX, and TEM. The greatest amount of the removed MB was achieved under definite conditions of solution pH 8.
View Article and Find Full Text PDFThis review paper examines the crucial role of nanowires in the field of quantum computing, highlighting their importance as versatile platforms for qubits and vital building blocks for creating fault-tolerant and scalable quantum information processing systems. Researchers are studying many categories of nanowires, including semiconductor, superconducting, and topological nanowires, to explore their distinct quantum features that play a role in creating various qubit designs. The paper explores the interdisciplinary character of quantum computing, combining the fields of quantum physics and materials science.
View Article and Find Full Text PDFThis comprehensive review examines the immense capacity of nanowires, nanostructures characterized by unbounded dimensions, to profoundly transform the field of biomedicine. Nanowires, which are created by combining several materials using techniques such as electrospinning and vapor deposition, possess distinct mechanical, optical, and electrical properties. As a result, they are well-suited for use in nanoscale electronic devices, drug delivery systems, chemical sensors, and other applications.
View Article and Find Full Text PDFIntroduction Carbapenem-resistant (CRE) infections have high mortality. We aimed to examine the diabetes mellitus (DM) association with CRE mortality. Methodology Our study is a retrospective cohort study including patients who were admitted to the medical wards in the main district hospital (New Jahra Hospital, Kuwait) between January 1, 2022, and January 1, 2023, and diagnosed with CRE infections during hospitalization.
View Article and Find Full Text PDFHO-modified graphite schist (GS) and sodium alginate (SA) interface was loaded by FeO nanoparticles (MNPs) to prepare a magnetic biosorbent that was employed in removing Mn(VII) from solutions. The prepared GS/SA/MNPs adsorbent was investigated using a variety of techniques, including elemental mapping, TEM, XPS, FTIR, FESEM, EDX, XRD, XPS, and zeta potential. An experimental study supported by statistical physics calculations was carried out to obtain a new outline of the Mn(VII) uptake mechanism.
View Article and Find Full Text PDFThis comprehensive review investigates a variety of creative approaches in the field of sustainable food packaging biomaterials in response to growing environmental concerns and the negative effects of traditional plastic packaging. The study carefully looks at new developments in biomaterials, such as biodegradable polymers, ceramics, composites, and metal alloys, in response to the growing need for environmentally suitable substitutes. It highlights how they might replace conventional plastic packaging and lessen environmental damage.
View Article and Find Full Text PDFHerein, a mixture of eggshell (ES) and magnetite nanoparticles (MNPs) was alkali-activated using NaOH/NaSiO solution and then, impregnated with sodium alginate (SA) to prepare a magnetic bio-based adsorbent (namely SAAES/SA/MNPs) for the decontamination of water containing basic dyes, in particular, methylene blue (MB) and crystal violet (CV). The physicochemical properties of magnetic spheres of SAAES/SA/MNPs were characterized using XRD, FTIR, FESEM, EDX, elemental mapping, TEM, and zeta potential techniques. Dye adsorption equilibrium was studied experimentally at pH 8.
View Article and Find Full Text PDFNanoparticles are minimal materials with unique physicochemical features that set them apart from bulk materials of the same composition. These properties make nanoparticles highly desirable for use in commercial and medical research. The primary intention for the development of nanotechnology is to achieve overarching social objectives like bettering our understanding of nature, boosting productivity, improving healthcare, and extending the bounds of sustainable development and human potential.
View Article and Find Full Text PDFThe design and simple, green preparation of dual-functional materials for the decontamination of both hazardous dyes and pathogenic microorganisms from wastewater remain challenging currently. Herein, a promising marine algal carbon-based material (named C-SA/SP) with both highly efficient dye adsorptive and antibacterial properties was fabricated based on the incorporation of sodium alginate and a low dose of silver phosphate via a facile and eco-friendly approach. The structure, removal of malachite green (MG) and congo red (CR), and their antibacterial performance were studied, and the adsorption mechanism was further interpreted by the statistical physics models, besides the classic models.
View Article and Find Full Text PDFJ Electr Bioimpedance
January 2022
Probing deep regions of the lung using electrical impedance is very important considering the need for a low cost and simple technique, particularly for the low and medium income countries. Because of complexity and cost, Electrical Impedance Tomography is not suitable for this envisaged application. The simple Tetrapolar Impedance Measurement (TPIM) technique employing four electrodes is the age old technique for bioelectrical measurements.
View Article and Find Full Text PDFGas (guest) molecules are trapped in hydrogen-bonded water molecules to form gas hydrates (GH), non-stoichiometric solids that resemble ice. High pressure and low temperature are typical conditions for their development, with van der Waals forces joining the host and guest molecules. This article study investigates the application of CO gas hydrates (CO GH) as a leavening agent in baking, with particular reference to the production of wheat bread.
View Article and Find Full Text PDFA polyaniline@Fe-ZSM-5 composite was synthesized via an in situ interfacial polymerization procedure. The morphology, crystallinity, and structural features of the as-developed PANI@Fe-ZSM-5 composite were assessed using scanning electron microscopy - energy dispersive spectroscopy (SEM-EDS), X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The composite was efficiently employed for the first time as an adsorbent Orange G (OG) dyestuff from water.
View Article and Find Full Text PDFBackground: The combination of sofosbuvir and daclatasvir has shown preliminary efficacy for hospitalized patients with COVID-19 in four open-label studies with small sample sizes. This larger trial aimed to assess if the addition of sofosbuvir/daclatasvir to standard care improved clinical outcomes in hospitalized patients with COVID-19.
Methods: This was a placebo-controlled, double-blind, randomized clinical trial in adults hospitalized with COVID-19 at 19 hospitals in Iran.
Nowadays, the global spreading of hazardous heavy metals becomes a top-priority environmental challenge, owing to its serious detrimental health outcomes. Herein, a novel cysteine-doped polyaniline@faujasite hybrid composite (Cys-PANi@FAU-50) was synthesized via a facile in-situ polymerization route for the effective detoxification of Cr(VI)-bearing wastewaters. The Cys-PANi@FAU-50 composite displayed an open mesoporous structure richly decorated with nitrogen/oxygen-containing functional groups, which consequently boosted the diffusion, adsorption and reduction of Cr(VI) oxyanions.
View Article and Find Full Text PDFChitosan was impregnated into porous activated coal to produce a multifunctional chitosan/activated coal (Cs/Ac) composite. The resulted Cs/Ac was characterized and utilized as a cost-effective adsorbent for Mn(VII) at altered temperatures (i.e.
View Article and Find Full Text PDFHydroxyapatite [Ca(PO)(OH)], an important biomaterial, retains a chemical structure that is similar to the mineral phase of bone. Consequently, the ability of hydroxyapatite (Hap) to augment bone growth within bone tissue has made it a potential candidate for use as a hard tissue-implant material. In this work, adopting a UV-mediated solid-state method for the first time, hydroxyapatite was synthesized from eggshells and no thermal treatment was used but ambient temperature was maintained.
View Article and Find Full Text PDFJ Antimicrob Chemother
November 2020
Objectives: Sofosbuvir and daclatasvir are direct-acting antivirals highly effective against hepatitis C virus. There is some in silico and in vitro evidence that suggests these agents may also be effective against SARS-CoV-2. This trial evaluated the effectiveness of sofosbuvir in combination with daclatasvir in treating patients with COVID-19.
View Article and Find Full Text PDFManganese-containing mica (Mn-mica) was synthesized at 200 °C/96 h using Mn-carbonate, Al-nitrate, silicic acid, and high KOH concentration under hydrothermal conditions. Mn-mica was characterized and tested as a new adsorbent for the removal of methyl orange (MO) dye from aqueous solutions. Compared to naturally occurring mica, the Mn-mica with manganese in the octahedral sheet resulted in enhanced MO uptake by four times at pH 3.
View Article and Find Full Text PDFSurfactant-modified exfoliated Fayum clay (CTAB-EC) obtained after chemical treatment with a CTAB/HO solution was further decorated with magnetic FeO nanoparticles (MNP). The final nanocomposite (MNP/CTAB-EC) was characterized by XRD, SEM, FTIR, TEM and its adsorptive capability against a model cationic dye, crystal violet (CV), was evaluated. A comparison of the adsorption performance of the raw clay and its modified counterparts using HO, CTAB, CTAB/HO or MNP indicated that the adsorption capacity of MNP/CTAB-EC was the highest for CV removal at pH 8.
View Article and Find Full Text PDFColorectal cancer (CRC) is the fourth most common cancer type globally. Investigating the signaling pathways that maintain cancer cell phenotype can identify new biomarkers for targeted therapy. Aberrant transforming growth factor-β (TGFβ) signaling has been implicated in CRC progression, however, the exact mechanism by which TGFβ exerts its function is still being unraveled.
View Article and Find Full Text PDFX-ray diffraction (XRD) and Energy-dispersive X-ray fluorescence spectrometer (EDXRF) are employed to investigate the microstructure of bulk specimens grown through the Bridgman technique and traveling heater process, respectively. We investigate the lattice parameters, grain sizes, and microstrains of the two grown samples. For a crystal grown by the vertical Bridgeman method, the vacancy serves as an acceptor, resulting in p-type conduction, whereas the vacancy expected to serve as a donor, occurring in n-type conduction for the crystal grown via the traveling heater technique.
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