Janus metallic film with gold and silver luster by electroless deposition of silver using poly(dopamine acrylamide) thin film.

Films that exhibit different metallic luster on the front and back, called Janus metallic films, have broad applications ranging from design materials to optical devices. However, the fabrication of these films is often a complicated process involving multiple metal deposition steps, thermal annealing, and calcination. Herein, we report the simple preparation of a Janus metallic film by electroless deposition of silver on a poly(dopamine acrylamide) (pDOPAm) thin film.

Order-order transitions in poly(-octadecyl acrylamide--hydroxyethyl acrylamide) statistical copolymer films.

This study demonstrates that a simple statistical copolymer can form self-assembled lamellae, whose structures depend on both the comonomer composition and the annealing temperature. Statistical copolymers of octadecyl acrylamide and hydroxyethyl acrylamide [p(ODA/HEAm)] were prepared free-radical copolymerization, and their thermal properties were studied by differential scanning calorimetry. Thin films of p(ODA/HEAm) were prepared spin-coating, and their structures were analyzed using X-ray diffraction.