Trailblazing Kr/Xe Separation: The Birth of the First Kr-Selective Material.

Efficient separation of Kr from Kr/Xe mixtures is pivotal in nuclear waste management and dark matter research. Thus far, scientists have encountered a formidable challenge: the absence of a material with the ability to selectively adsorb Kr over Xe at room temperature. This study presents a groundbreaking transformation of the renowned metal-organic framework (MOF) CuBTC, previously acknowledged for its Xe adsorption affinity, into an unparalleled Kr-selective adsorbent.

Self-Perpetuating Carbon Foam Microwave Plasma Conversion of Hydrocarbon Wastes into Useful Fuels and Chemicals.

White wastes (unseparated plastics, face masks, textiles, etc.) pose a serious challenge to sustainable human development and the ecosystem and have recently been exacerbated due to the surge in plastic usage and medical wastes from COVID-19. Current recycling methods such as chemical recycling, mechanical recycling, and incineration require either pre-sorting and washing or releasing CO.

Metal-Organic Framework-Polyacrylonitrile Composite Beads for Xenon Capture.

Mechanically robust forms of HKUST-1 metal-organic frameworks (MOFs) were fabricated by embedding the MOF crystals in a passive polyacrylonitrile (PAN) matrix at different MOF loadings of 10-90 mass %. PAN is highly porous and acts as a scaffold that holds the active MOF adsorbent in place. These MOF-PAN composites were then evaluated for capturing Xe.

Radiation-resistant metal-organic framework enables efficient separation of krypton fission gas from spent nuclear fuel.

Capture and storage of volatile radionuclides that result from processing of used nuclear fuel is a major challenge. Solid adsorbents, in particular ultra-microporous metal-organic frameworks, could be effective in capturing these volatile radionuclides, including Kr. However, metal-organic frameworks are found to have higher affinity for xenon than for krypton, and have comparable affinity for Kr and N.

Assessment of the Qualitative Fit Test and Quantitative Single-Pass Filtration Efficiency of Disposable N95 Masks Following Gamma Irradiation.

This quality improvement study examines the fit and filtration efficiency of disposable N95 masks after sterilization by cobalt-60 gamma irradiation.